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For example, n-butyl triflate can be written as CH 3 CH 2 CH 2 CH 2 OTf. The corresponding triflate anion, CF 3 SO − 3, is an extremely stable polyatomic ion; this comes from the fact that triflic acid (CF 3 SO 3 H) is a superacid; i.e. it is more acidic than pure sulfuric acid, already one of the strongest acids known.
Scandium trifluoromethanesulfonate, commonly called scandium triflate, is a chemical compound with formula Sc(SO 3 CF 3) 3, a salt consisting of scandium cations Sc 3+ and triflate SO 3 CF − 3 anions. Scandium triflate is used as a reagent in organic chemistry as a Lewis acid. [1]
Lanthanide triflates are proposed for Friedel-Crafts acylations and alkylations, which are often carried out with AlCl 3 as the catalyst in an organic solvent. The nature of the Friedel-Craft reaction, especially the acylation, forces the AlCl 3 to irreversibly complex with any oxygen-containing group in the product, with the only way of decomplexing it being to destroy the AlCl 3 part with ...
Silver trifluoromethanesulfonate, or silver triflate is the triflate (CF 3 SO 3 −) salt of Ag +. It is a white or colorless solid that is soluble in water and some organic solvents including, benzene. It is a reagent used in the synthesis of organic and inorganic triflates.
Trimethylsilyl trifluoromethanesulfonate (TMSOTf) is an organosilicon compound with the formula (CH 3) 3 SiO 3 SCF 3. It is a colorless moisture-sensitive liquid. It is the trifluoromethanesulfonate derivative of trimethylsilyl. [1] It is mainly used to activate ketones and aldehydes in organic synthesis.
Zinc trifluoromethanesulfonate or zinc triflate is the zinc salt of trifluoromethanesulfonic acid.It is commonly used as a Lewis acid catalyst, e.g. in silylations. [1]A white powder, zinc triflate is commercially available, though some workers have experienced inconsistent results with zinc triflate from different sources.
Concerns about exposure to Red Dye No. 3 in children and its potential association with adolescent hyperactivity have also been raised over the years — however, in a 2011 review, the FDA found ...
Hf(OTf) 4 mediated synthesis of altertoxins. Hf(OTf) 4, alongside Sc(OTf) 3 and In(OTf) 3, has been shown to activate alkynes and enable electrophilic substitution. In 2004 Song and Lee et al. reported Hf(OTf) 4-catalyzed Friedel-Crafts alkenylation of benzene with alkenyl derivatives. [7] Hf(OTf) 4 enabled electrophilic substitution of alkynes