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Figure 2. Two examples of RAFT agents. Typically, a RAFT polymerization system consists of: a radical source (e.g. thermochemical initiator or the interaction of gamma radiation with some reagent) monomer; RAFT agent; solvent (not strictly required if the monomer is a liquid)
An example of a simple chain reaction is the thermal decomposition of acetaldehyde (CH 3 CHO) to methane (CH 4) and carbon monoxide (CO). The experimental reaction order is 3/2, [4] which can be explained by a Rice-Herzfeld mechanism. [5] This reaction mechanism for acetaldehyde has 4 steps with rate equations for each step :
The classic example of a dehydration reaction is the Fischer esterification, which involves treating a carboxylic acid with an alcohol to give an ester RCO 2 H + R′OH ⇌ RCO 2 R′ + H 2 O. Often such reactions require the presence of a dehydrating agent, i.e. a substance that reacts with water.
In chemistry, a reagent (/ r i ˈ eɪ dʒ ən t / ree-AY-jənt) or analytical reagent is a substance or compound added to a system to cause a chemical reaction, or test if one occurs. [1] The terms reactant and reagent are often used interchangeably, but reactant specifies a substance consumed in the course of a chemical reaction. [ 1 ]
As a reagent, SMEAH is comparable with lithium aluminium hydride (LAH, LiAlH 4). It is a safer alternative to LAH and related hydrides. SMEAH exhibits similar reducing effects, but does not have the inconvenient pyrophoric nature, short shelf-life, or limited solubility of LAH. Upon contact with air and moisture, SMEAH reacts exothermically but ...
An example of organic reaction: oxidation of ketones to esters with a peroxycarboxylic acid Retrosynthetic analysis can be applied to design a complex synthesis reaction. Here the analysis starts from the products, for example by splitting selected chemical bonds, to arrive at plausible initial reagents.
the central organic synthesis reagent for hydroboration Dicyclohexylcarbodiimide: an organic compound; primary use is to couple amino acids during artificial peptide synthesis Diethyl azodicarboxylate: a valuable reagent but also quite dangerous and explodes upon heating Diethyl ether: organic compound; a common laboratory solvent Dihydropyran
In organic chemistry, a coupling reaction is a type of reaction in which two reactant molecules are bonded together. Such reactions often require the aid of a metal catalyst.