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Nickel(II) sulfate, or just nickel sulfate, usually refers to the inorganic compound with the formula NiSO 4 (H 2 O) 6. This highly soluble turquoise coloured salt is a common source of the Ni 2+ ion for electroplating. Approximately 40,000 tonnes were produced in 2005. [1]
NiSO 3 · 3 H 2 O: nickel(II) sulfite trihydrate light green [24] NiSO 3 •3N 2 H 4 · H 2 O: nickel(II) sulfite trihydrazine hydrate rose [5] NiSO 3 •2N 2 H 4 · H 2 O: nickel(II) sulfite dihydrazine hydrate blue [5] NiS 2 O 3 •6H 2 O Nickel(II) thiosulfate hexahydrate 463.03 orthorhombic 9.282 14.44 6.803 912.1 4 2.03 green [6]
Double fluorides include the above-mentioned fluoroanion salts, and those fluoronickelates such as NiF 4 and NiF 6.Other odd ones include an apple green coloured KNiF 3 ·H 2 O and NaNiF 3 ·H 2 O, aluminium nickel pentafluoride AlNiF 5 ·7H 2 O, ceric nickelous decafluoride Ce 2 NiF 10 ·7H 2 O, niobium nickel fluoride Ni 3 H 4 Nb 2 F 20 ·19H 2 O, vanadium nickel pentafluoride VNiF 5 ·7H 2 ...
K 2 Ni(SO 4) 2 · 6 H 2 O [13] Potassium Nickel Sulfate Hexahydrate [14] used as UV filter [48] Rb Ni Rb 2 [Ni(H 2 O) 6](SO 4) 2: Rubidium Nickel Sulfate Hexahydrate 6.221 12.41 9.131 106.055° 677.43 001 surface has step growth of 4.6 Å, optical transmission bands at 250, 500 and 860 nm which are the same as nickel sulfate hexahydrate, but UV ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
If the hydration energy is greater than the lattice energy, then the enthalpy of solution is negative (heat is released), otherwise it is positive (heat is absorbed). [3]The hydration energy should not be confused with solvation energy, which is the change in Gibbs free energy (not enthalpy) as solute in the gaseous state is dissolved. [4]
As a mineral the ammonium nickel salt, (NH 4) 2 Ni(SO 4) 2 · 6 H 2 O, can be called nickelboussingaultite. [38] With sodium, the double sulfate is nickelblödite Na 2 Ni(SO 4) 2 · 4 H 2 O from the blödite family. Nickel can be substituted by other divalent metals of similar sized to make mixtures that crystallise in the same form. [39]
The compound can be prepared by treating nickel or nickel(II) carbonate with acetic acid: . NiCO 3 + 2 CH 3 CO 2 H + 3 H 2 O → Ni(CH 3 CO 2) 2 ·4 H 2 O + CO 2. The mint-green tetrahydrate has been shown by X-ray crystallography to adopt an octahedral structure, the central nickel centre being coordinated by four water molecules and two acetate ligands. [5]