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The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
The Bohr–Sommerfeld model (also known as the Sommerfeld model or Bohr–Sommerfeld theory) was an extension of the Bohr model to allow elliptical orbits of electrons around an atomic nucleus. Bohr–Sommerfeld theory is named after Danish physicist Niels Bohr and German physicist Arnold Sommerfeld. Sommerfeld showed that, if electronic orbits ...
Bohr developed the Bohr model of the atom, in which he proposed that energy levels of electrons are discrete and that the electrons revolve in stable orbits around the atomic nucleus but can jump from one energy level (or orbit) to another. Although the Bohr model has been supplanted by other models, its underlying principles remain valid.
In 1913, Niels Bohr proposed a model of the atom, giving the arrangement of electrons in their sequential orbits. At that time, Bohr allowed the capacity of the inner orbit of the atom to increase to eight electrons as the atoms got larger, and "in the scheme given below the number of electrons in this [outer] ring is arbitrary put equal to the normal valency of the corresponding element".
His proposals were based on the then current Bohr model of the atom, in which the electron shells were orbits at a fixed distance from the nucleus. Bohr's original configurations would seem strange to a present-day chemist: sulfur was given as 2.4.4.6 instead of 1s 2 2s 2 2p 6 3s 2 3p 4 (2.8.6). Bohr used 4 and 6 following Alfred Werner's 1893 ...
The fine-structure constant gives the maximum positive charge of an atomic nucleus that will allow a stable electron-orbit around it within the Bohr model (element feynmanium). [20] For an electron orbiting an atomic nucleus with atomic number Z the relation is mv 2 / r = 1 / 4πε 0 Ze 2 / r 2 .
This pre-1925 period marked the old quantum theory built upon the Bohr-Sommerfeld model of the atom with its classical elliptical electron orbits. During the period between 1916 and 1925, much progress was being made concerning the arrangement of electrons in the periodic table.
The Bohr model of the chemical bond took into account the Coulomb repulsion - the electrons in the ring are at the maximum distance from each other. [2] Thus, according to this model, the methane molecule is a regular tetrahedron, in which center the carbon nucleus locates, and in the corners - the nucleus of hydrogen. The chemical bond between ...