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Anhydrous lanthanum(III) chloride can be produced by the ammonium chloride route. [3] [4] [5] In the first step, lanthanum oxide is heated with ammonium chloride to produce the ammonium salt of the pentachloride: La 2 O 3 + 10 NH 4 Cl → 2 (NH 4) 2 LaCl 5 + 6 H 2 O + 6 NH 3
The ammonium chloride route refers to a general procedure to produce anhydrous lanthanide chlorides. The method has the advantages of being general for the 14 lanthanides and it produces air-stable intermediates that resist hydrolysis. The use of ammonium chloride as a reagent is convenient because the salt is anhydrous, even when handled in air.
Pages in category "Lanthanum compounds" The following 44 pages are in this category, out of 44 total. ... Lanthanum(III) chloride; Lanthanum hydroxide; Lanthanum(III ...
Lanthanum fluoride is insoluble in water and can be used as a qualitative test for the presence of La 3+. The heavier halides are all very soluble deliquescent compounds. The anhydrous halides are produced by direct reaction of their elements, as heating the hydrates causes hydrolysis: for example, heating hydrated LaCl 3 produces LaOCl. [38]
Although most compounds are referred to by their IUPAC systematic names ... (table salt, rock salt) – NaCl; ... Lanthanum(III) sulfate – La 2 (SO 4) 3; Pb
The CuTi 2 structure of the lanthanum, cerium and praseodymium diiodides along with HP-NdI 2 contain 4 4 nets of metal and iodine atoms with short metal-metal bonds (393-386 La-Pr). [10] these compounds should be considered to be two-dimensional metals (two-dimensional in the same way that graphite is). The salt-like dihalides include those of ...
Lanthanum acetate is an inorganic compound, a salt of lanthanum with acetic acid with the chemical formula La(CH 3 CO 2) 3. According to X-ray crystallography, anhydrous lanthanum acetate is a coordination polymer. Each La(III) center is nine-coordinate, with two bidentate acetate ligands and the remaining sites occupied by oxygens provided by ...
The anhydrous compound can be produced by heating the hydrates to 300 °C. If heated further, anhydrous lanthanum(III) sulfate decomposes to La 2 O 2 SO 4 at 775 °C, which in turn decomposes to lanthanum(III) oxide at 1100 °C.