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The pump pulse is typically in the UV region and is often generated by a high-powered Nd:YAG laser, whereas the probe beam is in the infrared region. This technique currently operates down to the picosecond time regime and surpasses transient absorption and emission spectroscopy by providing structural information on the excited-state kinetics ...
Most systems use a Ti:Sapph gain medium due to the wide range of wavelengths that it can access. [3] [7] Typically, the same source is used to generate the pump and the probe. An optical parametric oscillator (OPO) is used to convert the probe beam to the desired wavelength. The probe wavelength can be tuned over a large range for spectroscopic ...
Another way of performing multi-color CRS is to use one picosecond laser with a narrow spectral bandwidth (<1 nm) as pump or Stokes and the other laser with broad spectral bandwidth. In this case, the spectrum of the transmitted broadband laser can be spread by a grating and measured by an array of detectors.
Stimulated Raman spectroscopy, also referred to as stimulated Raman scattering (SRS), is a form of spectroscopy employed in physics, chemistry, biology, and other fields. . The basic mechanism resembles that of spontaneous Raman spectroscopy: a pump photon, of the angular frequency , which is scattered by a molecule has some small probability of inducing some vibrational (or rotational ...
The final kinetic energy of the electron can be modeled by = + where the E B is the binding energy of the initial state, E kin is the kinetic energy of the photoemitted electron, Φ is the work function of the material in question, and E pump, E probe are the photon energies of the laser pulses, respectively.
Ultrafast nano-FTIR is a ready-to-use upgrade for nano-FTIR to enable pump-probe nano-spectroscopy at best-in-class spatial resolution. The same year the development of a cryo-neaSNOM – the first system of its kind to enable nanoscale near-field imaging & spectroscopy at cryogenic temperatures – was announced.
The measured spectra are used to determine the chemical composition and physical properties of astronomical objects (such as their temperature, density of elements in a star, velocity, black holes and more). [12] An important use for spectroscopy is in biochemistry. Molecular samples may be analyzed for species identification and energy content ...
In a broadband spectrometer, the visible pump beam is once again held at a fixed frequency, while the probe beam is spectrally broad. These laser beams overlap at a surface, but may access a wider range of molecular resonances simultaneously than a scanning spectrometer, and hence spectra can be acquired significantly faster, allowing the ...