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Some trajectories of a particle in a box according to Newton's laws of classical mechanics (A), and according to the Schrödinger equation of quantum mechanics (B–F). In (B–F), the horizontal axis is position, and the vertical axis is the real part (blue) and imaginary part (red) of the wave function.
Taking the "box" to be a black body cavity, the photons are continually being absorbed and re-emitted by the walls. When this is the case, the number of photons is not conserved. In the derivation of Bose–Einstein statistics , when the restraint on the number of particles is removed, this is effectively the same as setting the chemical ...
The particle in a one-dimensional potential energy box is the most mathematically simple example where restraints lead to the quantization of energy levels. The box is defined as having zero potential energy everywhere inside a certain region, and therefore infinite potential energy everywhere outside that region.
Unlike the infinite potential well, there is a probability associated with the particle being found outside the box. The quantum mechanical interpretation is unlike the classical interpretation, where if the total energy of the particle is less than the potential energy barrier of the walls it cannot be found outside the box.
The wave function of the ground state of a particle in a one-dimensional box is a half-period sine wave, which goes to zero at the two edges of the well. The energy of the particle is given by h 2 n 2 8 m L 2 {\textstyle {\frac {h^{2}n^{2}}{8mL^{2}}}} , where h is the Planck constant , m is the mass of the particle, n is the energy state ( n ...
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The Hamiltonians to which we know exact solutions, such as the hydrogen atom, the quantum harmonic oscillator and the particle in a box, are too idealized to adequately describe most systems. Using perturbation theory, we can use the known solutions of these simple Hamiltonians to generate solutions for a range of more complicated systems.