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Valence shell electron pair repulsion (VSEPR) theory (/ ˈ v ɛ s p ər, v ə ˈ s ɛ p ər / VESP-ər, [1]: 410 və-SEP-ər [2]) is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. [3]
Sulfur hexafluoride or sulphur hexafluoride (British spelling) is an inorganic compound with the formula SF 6. It is a colorless, odorless, non-flammable, and non-toxic gas. SF 6 has an octahedral geometry, consisting of six fluorine atoms attached to a central sulfur atom. It is a hypervalent molecule. [citation needed] Typical for a nonpolar ...
According to VSEPR theory, T-shaped geometry results when three ligands and two lone pairs of electrons are bonded to the central atom, written in AXE notation as AX 3 E 2. The T-shaped geometry is related to the trigonal bipyramidal molecular geometry for AX 5 molecules with three equatorial and two axial ligands.
Representative d-orbital splitting diagrams for square planar complexes featuring σ-donor (left) and σ+π-donor (right) ligands. A general d-orbital splitting diagram for square planar (D 4h) transition metal complexes can be derived from the general octahedral (O h) splitting diagram, in which the d z 2 and the d x 2 −y 2 orbitals are degenerate and higher in energy than the degenerate ...
For compounds with the formula MX 6, the chief alternative to octahedral geometry is a trigonal prismatic geometry, which has symmetry D 3h. In this geometry, the six ligands are also equivalent. There are also distorted trigonal prisms, with C 3v symmetry; a prominent example is W(CH 3) 6.
According to the VSEPR theory of molecular geometry, an axial position is more crowded because an axial atom has three neighboring equatorial atoms (on the same central atom) at a 90° bond angle, whereas an equatorial atom has only two neighboring axial atoms at a 90° bond angle. For molecules with five identical ligands, the axial bond ...
This was obvious long before VSEPR and even before electrons were known to exist. So diatomics are not an example of the use of VSEPR theory, even if some general chemistry books include them in a table of molecular geometries. For n = 10, 11 and 12 however, I cannot agree with Whoop Whoop Pull Up's repeated reversion of the edits by Double Sharp.
This geometry is almost always consistent with VSEPR theory, which usually explains non-collinearity of atoms with a presence of lone pairs. There are several variants of bending, where the most common is AX 2 E 2 where two covalent bonds and two lone pairs of the central atom (A) form a complete 8-electron shell .