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The chromate and dichromate ions are fairly strong oxidizing agents. Commonly three electrons are added to a chromium atom, reducing it to oxidation state +3. In acid solution the aquated Cr 3+ ion is produced. Cr 2 O 2− 7 + 14 H + + 6 e − → 2 Cr 3+ + 7 H 2 O ε 0 = 1.33 V. In alkaline solution chromium(III) hydroxide is produced.
Potassium dichromate, K 2 Cr 2 O 7, is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications. As with all hexavalent chromium compounds, it is acutely and chronically harmful to health.
Ammonium dichromate is an inorganic compound with the formula (NH 4) 2 Cr 2 O 7. In this compound, as in all chromates and dichromates, chromium is in a +6 oxidation state , commonly known as hexavalent chromium .
The change in equilibrium is visible by a change from yellow (chromate) to orange (dichromate), such as when an acid is added to a neutral solution of potassium chromate. At yet lower pH values, further condensation to more complex oxyanions of chromium is possible. Both the chromate and dichromate anions are strong oxidizing reagents at low pH ...
Structure of CrO(O 2) 2 (pyridine).Hydrogen atoms bonded to carbon atoms are omitted. Color code: Cr = gray, C= black, H = white, O= red, N = blue. Chromium(VI) oxide peroxide is formed by the addition of acidified hydrogen peroxide solutions to solutions of metal chromates or dichromates, such as sodium chromate or potassium dichromate.
More selective or gentler oxidizing reagents include pyridinium chlorochromate (PCC) and pyridinium dichromate (PDC). [1] Metal oxo species are capable of catalytic, including asymmetric oxidations of various types. Some metal-oxo complexes promote C-H bond activation, converting hydrocarbons to alcohols. [6] Selection of molecular metal oxides.
Sodium dichromate is the inorganic compound with the formula Na 2 Cr 2 O 7. However, the salt is usually handled as its dihydrate Na 2 Cr 2 O 7 ·2 H 2 O . Virtually all chromium ore is processed via conversion to sodium dichromate and virtually all compounds and materials based on chromium are prepared from this salt. [ 1 ]
Silver dichromate is a chemical compound with the formula Ag 2 Cr 2 O 7. It is insoluble in water and decomposes when treated with hot water. Its anion has a charge of -2.