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A reagent, termed the titrant or titrator, [2] is prepared as a standard solution of known concentration and volume. The titrant reacts with a solution of analyte (which may also be termed the titrand [3]) to determine the analyte's concentration. The volume of titrant that reacted with the analyte is termed the titration volume.
Differences in the temperature between the titrant and the titrand; Evaporative losses from the surface of the rapidly mixed fluid; Heats of solution when the titrant solvent is mixed with the analyte solvent; Heat introduced by the mechanical action of stirring (minor influence); and; Heat produced by the thermistor itself (very minor influence).
The ratio of peak areas between the internal standard and analyte is calculated to determine analyte concentration. [12] A common type of internal standard is an isotopically labeled analogue of the analyte, which incorporates one or more atoms of 2 H, 13 C, 15 N and 18 O into its structure. [13]
Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer
Most computerized databases will create a table of thermodynamic values using the values from the datafile. For MgCl 2 (c,l,g) at 1 atm pressure: Thermodynamic properties table for MgCl 2 (c,l,g), from the FREED datafile. Some values have truncated significant figures for display purposes. The table format is a common way to display ...
Titration is a family of techniques used to determine the concentration of an analyte. [8] Titrating accurately to either the half-equivalence point or the endpoint of a titration allows the chemist to determine the amount of moles used, which can then be used to determine a concentration or composition of the titrant.
The pH after the equivalence point depends on the concentration of the conjugate base of the weak acid and the strong base of the titrant. However, the base of the titrant is stronger than the conjugate base of the acid. Therefore, the pH in this region is controlled by the strong base. As such the pH can be found using the following: [1]
In that case, a constant ionic strength can be maintained, and [+] is known at all titration points if both [+] and [] are known (and should be directly related to primary standards). For instance, Martell and Motekaitis (1992) calculated the pH value expected at the start of the titration, having earlier titrated the acid and base solutions ...