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The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum state or the vacuum. If more ...
In chemistry, absolute configuration refers to the spatial arrangement of atoms within a molecular entity (or group) that is chiral, and its resultant stereochemical description. [1] Absolute configuration is typically relevant in organic molecules where carbon is bonded to four different substituents .
The video of an experiment showing vacuum fluctuations (in the red ring) amplified by spontaneous parametric down-conversion.. If the quantum field theory can be accurately described through perturbation theory, then the properties of the vacuum are analogous to the properties of the ground state of a quantum mechanical harmonic oscillator, or more accurately, the ground state of a measurement ...
A simple criterion for checking whether a density matrix is describing a pure or mixed state is that the trace of ρ 2 is equal to 1 if the state is pure, and less than 1 if the state is mixed. [ d ] [ 22 ] Another, equivalent, criterion is that the von Neumann entropy is 0 for a pure state, and strictly positive for a mixed state.
In quantum mechanics, the position operator is the operator that corresponds to the position observable of a particle. When the position operator is considered with a wide enough domain (e.g. the space of tempered distributions ), its eigenvalues are the possible position vectors of the particle.
The quantum wave equation can be solved using functions of position, (), or using functions of momentum, () and consequently the superposition of momentum functions are also solutions: = + The position and momentum solutions are related by a linear transformation, a Fourier transformation. This transformation is itself a quantum superposition ...
The position of each atom is determined by the nature of the chemical bonds by which it is connected to its neighboring atoms. The molecular geometry can be described by the positions of these atoms in space, evoking bond lengths of two joined atoms, bond angles of three connected atoms, and torsion angles ( dihedral angles ) of three ...
In atomic physics and quantum chemistry, Hund's rules refers to a set of rules that German physicist Friedrich Hund formulated around 1925, which are used to determine the term symbol that corresponds to the ground state of a multi-electron atom. The first rule is especially important in chemistry, where it is often referred to simply as Hund's ...