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The Laporte rule is a rule that explains the intensities of absorption spectra for chemical species. It is a selection rule that rigorously applies to atoms, and to molecules that are centrosymmetric, i.e. with an inversion centre.
Optical systems can be folded using plane mirrors; the system is still considered to be rotationally symmetric if it possesses rotational symmetry when unfolded. Any point on the optical axis (in any space) is an axial point. Rotational symmetry greatly simplifies the analysis of optical systems, which otherwise must be analyzed in three ...
Optical theory progressed in the mid-17th century with treatises written by philosopher René Descartes, which explained a variety of optical phenomena including reflection and refraction by assuming that light was emitted by objects which produced it. [26] This differed substantively from the ancient Greek emission theory.
AMO theory includes classical, semi-classical and quantum treatments. Typically, the theory and applications of emission, absorption, scattering of electromagnetic radiation (light) from excited atoms and molecules, analysis of spectroscopy, generation of lasers and masers, and the optical properties of matter in general, fall into these ...
It is not possible to describe the interaction of an optical electromagnetic wave with a metal using classical optical theory. Nonetheless, some of the main features can be described, at least in quantitative terms, provided the frequency dependence of conductivity and the role of free and bound electrons are taken into account.
Recording optical rotation with a polarimeter: The plane of polarisation of plane polarised light (4) rotates (6) as it passes through an optically active sample (5). This angle is determined with a rotatable polarizing filter (7). In chemistry, specific rotation ([α]) is a property of a chiral chemical compound.
Optical activity Photosensitivity A basic distinction is between isotropic materials, which exhibit the same properties regardless of the direction of the light, and anisotropic ones, which exhibit different properties when light passes through them in different directions.
An optical axis is an imaginary line that passes through the geometrical center of an optical system such as a camera lens, microscope or telescopic sight. [1] Lens elements often have rotational symmetry about the axis. The optical axis defines the path along which light propagates through the system, up to first approximation.