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CPVC sprinkler pipe inside a firestop mock-up. Chlorinated polyvinyl chloride (CPVC) is a thermoplastic produced by chlorination of polyvinyl chloride (PVC) resin. CPVC is significantly more flexible than PVC, and can also withstand higher temperatures. Uses include hot and cold water delivery pipes and industrial liquid handling.
This plastic bucket has been used as an open-air flowerpot for some years. Photodegradation has made it brittle, causing part of it to break off when the bucket was moved. In polymer chemistry, photo-oxidation (sometimes: oxidative photodegradation) is the degradation of a polymer surface due to the combined action of light and oxygen. [1]
Since that time, studies of PVC workers in Australia, Italy, Germany, and the UK have all associated certain types of occupational cancers with exposure to vinyl chloride, and it has become accepted that VCM is a carcinogen. [9]
Environmental Stress Cracking (ESC) is one of the most common causes of unexpected brittle failure of thermoplastic (especially amorphous) polymers known at present. According to ASTM D883, stress cracking is defined as "an external or internal crack in a plastic caused by tensile stresses less than its short-term mechanical strength".
This increase in elemental chlorine content contributes to CPVC's increased expression of chlorine-based characteristics, such as chemical durability, resistance to acids, bases, and salts; susceptibility to ammonia-based compounds, aromatics, esters, ketones; [9] chemical stability; heat energy transfer resistance. CPVC is commonly used in ...
Embrittlement is used to describe any phenomena where the environment compromises a stressed material's mechanical performance, such as temperature or environmental composition. This is oftentimes undesirable as brittle fracture occurs quicker and can much more easily propagate than ductile fracture, leading to complete failure of the equipment.
The more slip systems a metal has, the less brittle it is, because plastic deformation can occur along many of these slip systems. Conversely, with fewer slip systems, less plastic deformation can occur, and the metal will be more brittle. For example, HCP (hexagonal close packed) metals have few active slip systems, and are typically brittle.
Polymer degradation is the reduction in the physical properties of a polymer, such as strength, caused by changes in its chemical composition.Polymers and particularly plastics are subject to degradation at all stages of their product life cycle, including during their initial processing, use, disposal into the environment and recycling. [1]
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