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The Rado graph, an infinite graph that models exactly the first-order sentences that are almost always true of finite graphs. Glebskiĭ et al. (1969) and, independently, Fagin (1976) proved a zero–one law for first-order graph logic; Fagin's proof used the compactness theorem.
First-order approximation is the term scientists use for a slightly better answer. [3] Some simplifying assumptions are made, and when a number is needed, an answer with only one significant figure is often given ("the town has 4 × 10 3, or four thousand, residents"). In the case of a first-order approximation, at least one number given is exact.
The rate is first-order in one reactant (ethyl acetate), and also first-order in imidazole, which as a catalyst does not appear in the overall chemical equation. Another well-known class of second-order reactions are the S N 2 (bimolecular nucleophilic substitution) reactions, such as the reaction of n-butyl bromide with sodium iodide in acetone:
In mathematics, the moments of a function are certain quantitative measures related to the shape of the function's graph.If the function represents mass density, then the zeroth moment is the total mass, the first moment (normalized by total mass) is the center of mass, and the second moment is the moment of inertia.
Zero-order process (statistics), a sequence of random variables, each independent of the previous ones; Zero order process (chemistry), a chemical reaction in which the rate of change of concentration is independent of the concentrations; Zeroth-order approximation, an approximation of a function by a constant; Zeroth-order logic, a form of ...
first order The first order logic of graphs is a form of logic in which variables represent vertices of a graph, and there exists a binary predicate to test whether two vertices are adjacent. To be distinguished from second order logic, in which variables can also represent sets of vertices or edges.-flap
In fact, however, the observed reaction rate is second-order in NO 2 and zero-order in CO, [5] with rate equation r = k[NO 2] 2. This suggests that the rate is determined by a step in which two NO 2 molecules react, with the CO molecule entering at another, faster, step. A possible mechanism in two elementary steps that explains the rate ...
The second derivative of a function f can be used to determine the concavity of the graph of f. [2] A function whose second derivative is positive is said to be concave up (also referred to as convex), meaning that the tangent line near the point where it touches the function will lie below the graph of the function.