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The two dominant resonance forms of the phosphaethynolate anion localise negative charge on either the phosphorus or oxygen atoms meaning both are sites of nucleophilicity. [11] The same applies for the cyanate anion hence why PCO is observed to have similar pseudo-halogenic behaviour. [3] [12]
Contributing structures of the carbonate ion. In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or forms, [1] also variously known as resonance structures or canonical structures) into a resonance hybrid (or hybrid structure) in valence bond theory.
Another class of oxonium ions encountered in organic chemistry is the oxocarbenium ions, obtained by protonation or alkylation of a carbonyl group e.g. R−C= + −R′ which forms a resonance structure with the fully-fledged carbocation R− + −O−R′ and is therefore especially stable:
Satisfy the octet rule. Both oxygen atoms currently have 8 electrons assigned to them. The nitrogen atom has only 6 electrons assigned to it. One of the lone pairs on an oxygen atom must form a double bond, but either atom will work equally well. Therefore, there is a resonance structure. Tie up loose ends.
Carbon suboxide, or tricarbon dioxide, is an organic, oxygen-containing chemical compound with formula C 3 O 2 and structure O=C=C=C=O. Its four cumulative double bonds make it a cumulene. It is one of the stable members of the series of linear oxocarbons O=C n =O, which also includes carbon dioxide (CO 2) and pentacarbon dioxide (C 5 O 2).
Most notably hydroxyl radicals are produced from the decomposition of hydroperoxides (ROOH) or, in atmospheric chemistry, by the reaction of excited atomic oxygen with water. It is also an important radical formed in radiation chemistry, since it leads to the formation of hydrogen peroxide and oxygen , which can enhance corrosion and stress ...
The oxygen–oxygen bond lengths of 142.8 picometer are slightly shorter than the 146.4 pm oxygen–oxygen bonds in hydrogen peroxide. [7] Various dimeric and trimeric forms also seem to exist. There is a trend of increasing gas-phase acidity and corresponding p K a as the number of oxygen atoms in the chain increases in HO n H structures ( n ...
Oxygen can form oxides with heavier noble gases xenon and radon, although this needs indirect methods. Even though no oxides of krypton are known, oxygen is able to form covalent bonds with krypton in an unstable compound Kr(OTeF 5) 2. One unexpected oxygen compound is dioxygenyl hexafluoroplatinate, O + 2 PtF −