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The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
This can be due to temperature changes, solvent evaporation, or by mixing solvents. Precipitation occurs more rapidly from a strongly supersaturated solution. The formation of a precipitate can be caused by a chemical reaction. When a barium chloride solution reacts with sulphuric acid, a white precipitate of barium sulphate is formed.
Salting out (also known as salt-induced precipitation, salt fractionation, anti-solvent crystallization, precipitation crystallization, or drowning out) [1] is a purification technique that utilizes the reduced solubility of certain molecules in a solution of very high ionic strength.
Very soluble <1 calcium nitrate: 158.7 0.63 Freely soluble 1 to 10 calcium chloride: 65 1.54 Soluble 10 to 30 sodium oxalate: 3.9 26 Sparingly soluble 30 to 100 Slightly soluble 100 to 1000 calcium sulfate: 0.21 490 Very slightly soluble 1000 to 10,000 dicalcium phosphate: 0.02 5000 Practically insoluble or insoluble ≥ 10,000 barium sulfate ...
A practical example used very widely in areas drawing drinking water from chalk or limestone aquifers is the addition of sodium carbonate to the raw water to reduce the hardness of the water. In the water treatment process, highly soluble sodium carbonate salt is added to precipitate out sparingly soluble calcium carbonate.
Ammonium sulfate is an inorganic salt with a high solubility that disassociates into ammonium (NH + 4) and sulfate (SO 2− 4) in aqueous solutions. [1] Ammonium sulfate is especially useful as a precipitant because it is highly soluble, stabilizes protein structure, has a relatively low density, is readily available, and is relatively inexpensive.
2) salts of lead. The sulfide can also be precipitated from acetate solutions. These salts are all poorly soluble in water. Among the halides, the iodide is less soluble than the bromide, which, in turn, is less soluble than the chloride. [3] Lead(II) oxide is also soluble in alkali hydroxide solutions to form the corresponding plumbite salt. [2]
The minerals precipitate out of solution in the reverse order of their solubilities, such that the order of precipitation from sea water is: Calcite (CaCO 3) and dolomite (CaMg(CO 3) 2) Gypsum (CaSO 4 · 2 H 2 O) and anhydrite (CaSO 4). Halite (i.e. common salt, NaCl) Potassium and magnesium salts