Search results
Results from the WOW.Com Content Network
The Kelvin equation describes the change in vapour pressure due to a curved liquid–vapor interface, such as the surface of a droplet. The vapor pressure at a convex curved surface is higher than that at a flat surface. The Kelvin equation is dependent upon thermodynamic principles and does not allude to special properties of materials.
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
With a constant pressure, the voltage needed to cause an arc reduced as the gap size was reduced but only to a point. As the gap was reduced further, the voltage required to cause an arc began to rise and again exceeded its original value. For a given gas, the voltage is a function only of the product of the pressure and gap length.
Also, the familiar relationship that stagnation pressure is equal to total pressure does not always hold true. (It is always true in isentropic flow, but the presence of shock waves can cause the flow to depart from isentropic.) As a result, pressure coefficients can be greater than one in compressible flow. [4]
Darcy's law is an equation that describes the flow of a fluid through a porous medium and through a Hele-Shaw cell.The law was formulated by Henry Darcy based on results of experiments [1] on the flow of water through beds of sand, forming the basis of hydrogeology, a branch of earth sciences.
The total force vector acting at the center of pressure is the surface integral of the pressure vector field across the surface of the body. The resultant force and center of pressure location produce an equivalent force and moment on the body as the original pressure field. Pressure fields occur in both static and dynamic fluid mechanics ...
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
Δp is the pressure difference between the two ends, L is the length of pipe, μ is the dynamic viscosity, Q is the volumetric flow rate, R is the pipe radius, A is the cross-sectional area of pipe. The equation does not hold close to the pipe entrance. [8]: 3 The equation fails in the limit of low viscosity, wide and/or short pipe.