Search results
Results from the WOW.Com Content Network
Boric acid is a weak acid, with pK a (the pH at which buffering is strongest because the free acid and borate ion are in equal concentrations) of 9.24 in pure water at 25 °C. But apparent p K a is substantially lower in swimming pool or ocean waters because of interactions with various other molecules in solution.
The most common soluble poison in commercial pressurized water reactors (PWR) is boric acid, which is often referred to as soluble boron. The boric acid in the coolant decreases the thermal utilization factor, causing a decrease in reactivity. By varying the concentration of boric acid in the coolant, a process referred to as boration and ...
Potassium fluoroborate is obtained by treating potassium carbonate with boric acid and hydrofluoric acid. B(OH) 3 + 4 HF → HBF 4 + 3 H 2 O 2 HBF 4 + K 2 CO 3 → 2 KBF 4 + H 2 CO 3. Fluoroborates of alkali metals and ammonium ions crystallize as water-soluble hydrates with the exception of potassium, rubidium, and cesium.
Boric acid will initially decompose into steam, (H 2 O (g)) and metaboric acid (HBO 2) at around 170 °C, and further heating above 300 °C will produce more steam and diboron trioxide. The reactions are: H 3 BO 3 → HBO 2 + H 2 O 2 HBO 2 → B 2 O 3 + H 2 O. Boric acid goes to anhydrous microcrystalline B 2 O 3 in a heated fluidized bed. [22 ...
Boron trifluoride reacts with water to give boric acid and fluoroboric acid. The reaction commences with the formation of the aquo adduct, H 2 O−BF 3, which then loses HF that gives fluoroboric acid with boron trifluoride. [22] 4 BF 3 + 3 H 2 O → 3 H[BF 4] + B(OH) 3. The heavier trihalides do not undergo analogous reactions, possibly due to ...
Tetraboric acid or pyroboric acid is a chemical compound with empirical formula H 2 B 4 O 7. [2] It is a colourless water-soluble solid formed by the dehydration or polymerization boric acid. Tetraboric acid is formally the parent acid of the tetraborate anion [B 4 O 7] 2−.
This reaction is very fast, with characteristic time less than 10 μs. [13] Polymeric boron oxoanions are formed in aqueous solution of boric acid at pH 7–10 if the boron concentration is higher than about 0.025 mol/L.
The reaction of boron trichloride with alcohols was reported in 1931, and was used to prepare dimethoxyboron chloride, B(OCH 3) 2 Cl. [3] Egon Wiberg and Wilhelm Ruschmann used it to prepare tetrahydroxydiboron by first introducing the boron–boron bond by reduction with sodium and then hydrolysing the resulting tetramethoxydiboron, B 2 (OCH 3) 4, to produce what they termed sub-boric acid. [4]