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Copper(I) iodide reacts with mercury vapors to form brown copper(I) tetraiodomercurate(II): 4 CuI + Hg → (Cu +) 2 [HgI 4] 2− + 2 Cu. This reaction can be used for the detection of mercury since the white CuI to brown Cu 2 [HgI 4] color change is dramatic. Copper(I) iodide is used in the synthesis of Cu(I) clusters such as [Cu 6 I 7] −. [10]
Copper(I) iodide is a solid pale tan material transforming at 60–62 °C to orange color. [17] Ammonium metavanadate is a white material, turning to brown at 150 °C and then to black at 170 °C. [17] Manganese violet (Mn(NH 4) 2 P 2 O 7) is a violet material, a popular pigment, turning to white at 400 °C. [17]
Upon heating the solid to 146 °C, this material adopts the alpha-polymorph. In this form, the iodide ions form a rigid cubic framework, and the Ag+ centers are molten. The electrical conductivity of the solid increases by 4000x. Similar behavior is observed for copper(I) iodide (CuI), rubidium silver iodide (RbAg 4 I 5), [9] and Ag 2 HgI 4.
For a gas, it is the hypothetical state the gas would assume if it obeyed the ideal gas equation at a pressure of 1 bar. For a gaseous or solid solute present in a diluted ideal solution , the standard state is the hypothetical state of concentration of the solute of exactly one mole per liter (1 M ) at a pressure of 1 bar extrapolated from ...
Oxygen-balanced mixture has theoretical maximum density of 5.109 g/cm 3, adiabatic flame temperature 2843 K (phase transitions included) with the aluminum oxide being molten and copper in both liquid and gaseous form; 343 g of copper vapor per kg of this thermite are produced. The energy content is 974 cal/g.
For gases, departure from 3 R per mole of atoms is generally due to two factors: (1) failure of the higher quantum-energy-spaced vibration modes in gas molecules to be excited at room temperature, and (2) loss of potential energy degree of freedom for small gas molecules, simply because most of their atoms are not bonded maximally in space to ...
The only affordable material that has similar corrosion resistance to copper is stainless steel. However, the thermal conductivity of stainless steel is 1/30th times than that of copper. Aluminum tubes are not suitable for potable or untreated water applications because it corrodes at pH<7.0 and so it releases hydrogen gas. [8] [9] [10]
The low solubility of silver iodide and lead iodide reflects the covalent character of these metal iodides. A test for the presence of iodide ions is the formation of yellow precipitates of these compounds upon treatment of a solution of silver nitrate or lead(II) nitrate. [2] Aqueous solutions of iodide salts dissolve iodine better than pure ...