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It is defined as one kilocalorie of energy (1000 thermochemical gram calories) per one mole of substance. The unit symbol is written kcal/mol or kcal⋅mol −1. As typically measured, one kcal/mol represents a temperature increase of one degree Celsius in one liter of water (with a mass of 1 kg) resulting from the reaction of one mole of reagents.
The nitrophosphate process (also known as the Odda process) is a method for the industrial production of nitrogen fertilizers invented by Erling Johnson in the municipality of Odda, Norway around 1927. The process involves acidifying phosphate rock with dilute nitric acid to produce a mixture of phosphoric acid and calcium nitrate.
The Frank–Caro process was the first commercial process that was used worldwide to fix atmospheric nitrogen. The product was used as fertilizer and commercially known as Lime-Nitrogen. Nitrolim or Kalkstickstoff in German. [1] The method was developed by the German chemists Adolph Frank and Nikodem Caro between 1895 and 1899. In its first ...
The SI unit of molar heat capacity is joule per kelvin per mole, J⋅K −1 ⋅mol −1. Like the specific heat, the measured molar heat capacity of a substance, especially a gas, may be significantly higher when the sample is allowed to expand as it is heated ( at constant pressure , or isobaric ) than when it is heated in a closed vessel that ...
Total nitrogenous fertilizer consumption per region, measured in tonnes of total nutrient per year. Nitrogen fertilizers are made from ammonia (NH 3) produced by the Haber–Bosch process. [28] In this energy-intensive process, natural gas (CH 4) usually supplies the hydrogen, and the nitrogen (N 2) is derived from the air.
The history of the Haber process begins with the invention of the Haber process at the dawn of the twentieth century. The process allows the economical fixation of atmospheric dinitrogen in the form of ammonia, which in turn allows for the industrial synthesis of various explosives and nitrogen fertilizers, and is probably the most important industrial process developed during the twentieth ...
The carbide powder is heated at about 1000 °C in an electric furnace into which nitrogen is passed for several hours. [12] The product is cooled to ambient temperatures and any unreacted carbide is leached out cautiously with water. CaC 2 + N 2 → CaCN 2 + C (ΔH o f = –69.0 kcal/mol at 25 °C)
The Birkeland–Eyde process was one of the competing industrial processes in the beginning of nitrogen-based fertilizer production. It is a multi-step nitrogen fixation reaction that uses electrical arcs to react atmospheric nitrogen (N 2) with oxygen (O 2), ultimately producing nitric acid (HNO 3) with water. [1]