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Tetrahydrofuran (THF), or oxolane, is an organic compound with the formula (CH 2) 4 O. The compound is classified as heterocyclic compound , specifically a cyclic ether . It is a colorless, water- miscible organic liquid with low viscosity .
It is produced by polymerization of tetrahydrofuran as well as 1,4-butanediol. The product is commercially available as polymers of low average molecular weights , between 250 and 3000 daltons . In this form it is a white waxy solid that melts between 20 and 30 °C.
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2,2,5,5-tetramethyltetrahydrofuran (TMTHF) or 2,2,5,5-tetramethyloxolane (TMO) is a heterocyclic compound with the formula C 8 H 16 O, or (CH 3) 2 (C(CH 2) 2 OC)(CH 3) 2.It can be seen as derivative of tetrahydrofuran (oxolane) with four methyl groups replacing four hydrogen atoms on each of the carbon atoms in the ring that are adjacent to the oxygen.
Deuterated tetrahydrofuran (d 8-THF) is a colourless, organic liquid at standard temperature and pressure. [1] This heterocyclic compound has the chemical formula C 4 D 8 O, and is an isotopologue of tetrahydrofuran. [2] Deuterated THF is used as a solvent in NMR spectroscopy, though its expense can often be prohibitive. [citation needed]
2-Methyltetrahydrofuran (2-MeTHF) is an organic compound with the molecular formula C 5 H 10 O. It is a highly flammable, mobile liquid. It is mainly used as a replacement for Tetrahydrofuran (THF) in specialized applications for its better performance, such as to obtain higher reaction temperatures, or easier separations (as, unlike THF, it is not miscible with water).
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For example, tetrahydrofuran-3-one (3-ketotetrahydrofuran) [12] and 3-aminotetrahydrofuran [13] have been synthesized from 3-hydroxytetrahydrofuran and used in pharmaceutical syntheses. Additionally, additive amounts (0.05-0.15 weight %) of the nitrate ester manufactured by sulfuric acid - nitric acid nitration of 3-hydoxytetrahydrofuran have ...
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