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  2. Redundancy principle (biology) - Wikipedia

    en.wikipedia.org/wiki/Redundancy_principle_(biology)

    How nature sets the disproportionate numbers of particles remain unclear, but can be found using the theory of diffusion. One example is the number of neurotransmitters around 2000 to 3000 released during synaptic transmission, that are set to compensate the low copy number of receptors, so the probability of activation is restored to one. [19 ...

  3. Double-exchange mechanism - Wikipedia

    en.wikipedia.org/wiki/Double-exchange_mechanism

    The double-exchange mechanism is a type of a magnetic exchange that may arise between ions in different oxidation states.First proposed by Clarence Zener, [1] this theory predicts the relative ease with which an electron may be exchanged between two species and has important implications for whether materials are ferromagnetic, antiferromagnetic, or exhibit spiral magnetism. [2]

  4. Pyruvate decarboxylation - Wikipedia

    en.wikipedia.org/wiki/Pyruvate_decarboxylation

    Pyruvate decarboxylation or pyruvate oxidation, also known as the link reaction (or oxidative decarboxylation of pyruvate [1]), is the conversion of pyruvate into acetyl-CoA by the enzyme complex pyruvate dehydrogenase complex.

  5. Hydrogenase - Wikipedia

    en.wikipedia.org/wiki/Hydrogenase

    In fact, its catalytic activity is more effective than platinum, which is the best-known catalyst for the H 2 evolution reaction. [38] Among three different types of hydrogenases, [FeFe] hydrogenases is considered as a strong candidate for an integral part of the solar H 2 production system since they offer an additional advantage of high TOF ...

  6. Nernst equation - Wikipedia

    en.wikipedia.org/wiki/Nernst_equation

    When an oxidizer (Ox) accepts a number z of electrons ( e −) to be converted in its reduced form (Red), the half-reaction is expressed as: + The reaction quotient (Q r), also often called the ion activity product (IAP), is the ratio between the chemical activities (a) of the reduced form (the reductant, a Red) and the oxidized form (the oxidant, a Ox).

  7. Woodward–Hoffmann rules - Wikipedia

    en.wikipedia.org/wiki/Woodward–Hoffmann_rules

    Thermolysis converts 1 to (E,E) geometric isomer 2, but 3 to (E,Z) isomer 4.. The Woodward–Hoffmann rules (or the pericyclic selection rules) [1] are a set of rules devised by Robert Burns Woodward and Roald Hoffmann to rationalize or predict certain aspects of the stereochemistry and activation energy of pericyclic reactions, an important class of reactions in organic chemistry.

  8. Alternative oxidase - Wikipedia

    en.wikipedia.org/wiki/Alternative_oxidase

    The alternative oxidase is an integral monotopic membrane protein that is tightly bound to the inner mitochondrial membrane from matrix side [18] The enzyme has been predicted to contain a coupled diiron center on the basis of a conserved sequence motif consisting of the proposed iron ligands, four glutamate and two histidine amino acid residues. [19]

  9. Photosystem I - Wikipedia

    en.wikipedia.org/wiki/Photosystem_I

    The two modified chlorophyll molecules are early electron acceptors in PSI. They are present one per PsaA/PsaB side, forming two branches electrons can take to reach F x. A 0 accepts electrons from P700*, passes it to A 1 of the same side, which then passes the electron to the quinone on the same side. Different species seems to have different ...