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Group 13 hydrides are chemical compounds containing group 13-hydrogen bonds (elements of group 13: boron, aluminium, gallium, indium, thallium, and nihonium). [ 1 ] Trihydrides
This family of boron hydrides includes mono- and dialkylboranes. The simplest members readily engage in redistribution reactions: 2 BH 2 (CH 3) → BH(CH 3) 2 + 0.5 B 2 H 6. With bulky substituents, primary and secondary boranes are more readily isolable and even useful. Examples include thexylborane and 9-BBN. Almost all primary and secondary ...
Boron hydride clusters are compounds with the formula B x H y or related anions, where x ≥ 3. Many such cluster compounds are known. Common examples are those with 5, 10, and 12 boron atoms. Although they have few practical applications, the borane hydride clusters exhibit structures and bonding that differs strongly from the patterns seen in ...
These hydrides are formed by all the true non-metals (except zero group elements) and the elements like Al, Ga, Sn, Pb, Bi, Po, etc., which are normally metallic in nature, i.e., this class includes the hydrides of p-block elements. In these substances the hydride bond is formally a covalent bond much like the bond made by a proton in a weak ...
The elements in group 13 are also capable of forming stable compounds with the halogens, usually with the formula MX 3 (where M is a boron-group element and X is a halogen.) [14] Fluorine, the first halogen, is able to form stable compounds with every element that has been tested (except neon and helium), [15] and the boron group is no exception.
Often the boron in borides has fractional oxidation states, such as −1/3 in calcium hexaboride (CaB 6). From the structural perspective, the most distinctive chemical compounds of boron are the hydrides. Included in this series are the cluster compounds dodecaborate (B 12 H 2− 12), decaborane (B 10 H 14), and the carboranes such as C 2 B 10 ...
Structure of a rare monomeric boron hydride, R = i-Pr. [4] The most-studied class of organoboron compounds has the formula BR n H 3−n. These compounds are catalysts, reagents, and synthetic intermediates. The trialkyl and triaryl derivatives feature a trigonal-planar boron center that is typically only weakly Lewis acidic.
Pyrolysis of diborane gives boron hydride clusters, such as pentaborane(9) B 5 H 9 and decaborane B 10 H 14. [55]: 164, 170, 173 A large number of anionic boron hydrides are also known, e.g. [B 12 H 12] 2−. In these cluster compounds, boron has a coordination number greater than four. [51]