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The macroscopic energy equation for infinitesimal volume used in heat transfer analysis is [6] = +, ˙, where q is heat flux vector, −ρc p (∂T/∂t) is temporal change of internal energy (ρ is density, c p is specific heat capacity at constant pressure, T is temperature and t is time), and ˙ is the energy conversion to and from thermal ...
The process of heat transfer from one place to another place without the movement of particles is called conduction, such as when placing a hand on a cold glass of water—heat is conducted from the warm skin to the cold glass, but if the hand is held a few inches from the glass, little conduction would occur since air is a poor conductor of heat.
Thermal radiation is electromagnetic radiation emitted by the thermal motion of particles in matter. All matter with a temperature greater than absolute zero emits thermal radiation. The emission of energy arises from a combination of electronic, molecular, and lattice oscillations in a material. [1]
Conduction is the main mode of heat transfer for solid materials because the strong inter-molecular forces allow the vibrations of particles to be easily transmitted, in comparison to liquids and gases. Liquids have weaker inter-molecular forces and more space between the particles, which makes the vibrations of particles harder to transmit.
In microscopic terms, heat is a transfer quantity, and is described by a transport theory, not as steadily localized kinetic energy of particles. Heat transfer arises from temperature gradients or differences, through the diffuse exchange of microscopic kinetic and potential particle energy, by particle collisions and other interactions.
In a statistical mechanical account of an ideal gas, in which the molecules move independently between instantaneous collisions, the internal energy is just the sum total of the gas's independent particles' kinetic energies, and it is this kinetic motion that is the source and the effect of the transfer of heat across a system's boundary. For a ...
Transfers of energy as work, or as heat, or of matter, between the system and the surroundings, take place through the walls, according to their respective permeabilities. Matter or energy that pass across the boundary so as to effect a change in the internal energy of the system need to be accounted for in the energy balance equation.
The flow of heat is a form of energy transfer. Heat transfer is the natural process of moving energy to or from a system, other than by work or the transfer of matter. In a diathermal system, the internal energy can only be changed by the transfer of energy as heat: =.