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The three possible arrangements of the nitro groups afford three isomers, 1,2-dinitrobenzene, 1,3-dinitrobenzene, and 1,4-dinitrobenzene. Each isomer has the chemical formula C 6 H 4 N 2 O 4 and a molar mass of about 168.11 g/mol. 1,3-Dinitrobenzene is the most common isomer and it is used in the manufacture of explosives.
1,2-Dinitrobenzene is one of three isomers of dinitrobenzene, with the formula C 6 H 4 (NO 2) 2. The compound is a white or colorless solid that is soluble in organic solvents. It is prepared from 2-nitroaniline by diazotization and treatment with sodium nitrite in the presence of a copper catalyst. [1]
In contrast, 2-methyl-1,4-dinitrobenzene (2c) is isolated in only 9.9% yield. [4] As witnessed in the above example, when a π-acceptor substituent (πAS) is meta to a π-donor substituent (πDS), the electrophilic aromatic nitration occurs ortho to the πAS rather than para.
Nitrobenzenes are a group of nitro compounds consisting of one or more nitro groups as substituents on a benzene core. They have the formula C 6 H 6–n (NO 2) n, where n = 1–6 is the number of nitro groups. Depending on the number of nitro groups, there may be several constitutional isomers possible. Mononitrobenzene; Dinitrobenzene. 1,2 ...
A comparison of S N 1 to S N 2 reactions is to the right. On the left is an S N 1 reaction coordinate diagram. Note the decrease in ΔG ‡ activation for the polar-solvent reaction conditions. This arises from the fact that polar solvents stabilize the formation of the carbocation intermediate to a greater extent than the non-polar-solvent ...
Hansen solubility parameters were developed by Charles M. Hansen in his Ph.D thesis in 1967 [1] [2] as a way of predicting if one material will dissolve in another and form a solution. [3] They are based on the idea that like dissolves like where one molecule is defined as being 'like' another if it bonds to itself in a similar way.
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Ball-and-stick model of a 1,2-dinitrobenzene molecule, C 6 H 4 N 2 O 4, also known as ortho-dinitrobenzene or o-dinitrobenzene. The molecule is shown as found in the crystal structure reported in Acta Crystallogr. B (1990) 46, 567–572 and CSD entry ZZZFYW01. Colour code: Carbon, C: grey Hydrogen, H: white Nitrogen, N: blue