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Sodium thiosulfate (sodium thiosulphate) is an inorganic compound with the formula Na 2 S 2 O 3 ·(H 2 O) x. Typically it is available as the white or colorless pentahydrate (x = 5), which is a white solid that dissolves well in water. The compound is a reducing agent and a ligand, and these properties underpin its applications. [2]
Thiosulfate (IUPAC-recommended spelling; sometimes thiosulphate in British English) is an oxyanion of sulfur with the chemical formula S 2 O 2− 3.Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid, such as sodium thiosulfate Na 2 S 2 O 3 and ammonium thiosulfate (NH 4) 2 S 2 O 3.
12.69 is the conversion factor from mEq sodium thiosulfate to grams of iodine (the molecular weight of iodine is 126.9 g/mol); W is the weight of the sample in grams. The determination of IV according to Wijs is the official method currently accepted by international standards such as DIN 53241-1:1995-05, AOCS Method Cd 1-25, EN 14111 and ISO ...
Sodium tetrathionate is formed by the oxidation of sodium thiosulfate (Na 2 S 2 O 3), e.g. by the action of iodine: [1] 2 Na 2 S 2 O 3 + I 2 → Na 2 S 4 O 6 + 2 NaI. The reaction is signaled by the decoloration of iodine. This reaction is the basis of iodometric titrations. Other methods include the coupling of sodium bisulfite with disulfur ...
Thioglycolic acid is prepared by reaction of sodium or potassium chloroacetate with alkali metal hydrosulfide in aqueous medium. [19] It can be also prepared via the Bunte salt obtained by reaction of sodium thiosulfate with chloroacetic acid: [7] [20] ClCH 2 CO 2 H + Na 2 S 2 O 3 → Na[O 3 S 2 CH 2 CO 2 H] + NaCl Na[O 3 S 2 CH 2 CO 2 H] + H 2 ...
The related sodium thiosulfate also dechlorinates water. Campden tablets are also useful for decontamination and neutralization after exposure to tear gas. [4] The molar mass (commonly called molecular weight or MW) of potassium metabisulfite is 222 g/mol, and that of sodium metabisulfite is 190 g/mol.
From the above equations it can be seen that 2 moles of thiosulfate is equivalent to 70.9 grams (2.50 ounces) of active chlorine. Again the percentage of available chlorine can be calculated through the concept of normality. The gram equivalent of bleaching powder is equal to the gram equivalent of the standard titrant used.
Sodium sulfate is a typical electrostatically bonded ionic sulfate. The existence of free sulfate ions in solution is indicated by the easy formation of insoluble sulfates when these solutions are treated with Ba 2+ or Pb 2+ salts: Na 2 SO 4 + BaCl 2 → 2 NaCl + BaSO 4. Sodium sulfate is unreactive toward most oxidizing or reducing agents.