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Bromobutane (molecular formula: C 4 H 9 Br, molar mass: 137.02 g/mol) may refer to either of two chemical compounds: 1-Bromobutane (n-butyl bromide)
2 Li + C 4 H 9 X → C 4 H 9 Li + LiX where X = Cl, Br. The lithium for this reaction contains 1-3% sodium. When bromobutane is the precursor, the product is a homogeneous solution, consisting of a mixed cluster containing both LiBr and LiBu. 1-Fluorobutane can be obtained by reacting 1-bromobutane with potassium fluoride in ethylene glycol. [5]
2-Bromobutane is an isomer of 1-bromobutane. Both compounds share the molecular formula C 4 H 9 Br. 2-Bromobutane is also known as sec-butyl bromide or methylethylbromomethane. Because it contains bromine, a halogen, it is part of a larger class of compounds known as alkyl halides. It is a colorless liquid with a pleasant odor.
[2] [3] [4] The ring-flip of substituted cyclohexanes constitutes a common form of conformers. [5] The study of the energetics of bond rotation is referred to as conformational analysis. [6] In some cases, conformational analysis can be used to predict and explain product selectivity, mechanisms, and rates of reactions. [7]
The most common one in nature (myo-inositol) has the hydroxyls on carbons 1, 2, 3 and 5 on the same side of that plane, and can therefore be called cis-1,2,3,5-trans-4,6-cyclohexanehexol. And each of these cis - trans isomers can possibly have stable "chair" or "boat" conformations (although the barriers between these are significantly lower ...
[2] [3] The term metamer was formerly used for the same concept. [4] For example, butanol H 3 C−(CH 2) 3 −OH, methyl propyl ether H 3 C−(CH 2) 2 −O−CH 3, and diethyl ether (H 3 CCH 2 −) 2 O have the same molecular formula C 4 H 10 O but are three distinct structural isomers. The concept applies also to polyatomic ions with the same ...
Solid Mn 3 O 4: −1387 Permanganate: Aqueous MnO − 4: −543 Mercury(II) oxide (red) Solid HgO −90.83 Mercury sulfide (red, cinnabar) Solid HgS −58.2 Nitrogen: Gas N 2: 0 Ammonia (ammonium hydroxide) Aqueous NH 3 (NH 4 OH) −80.8 Ammonia: Gas NH 3: −46.1 Ammonium nitrate: Solid NH 4 NO 3: −365.6 Ammonium chloride: Solid NH 4 Cl − ...
Conversion of glucose to fructose by xylose isomerase was first patented in the 1960s. However, the process was not industrially practical as the enzymes were in solution, and recycling the enzyme was problematic. [7] An immobile xylose isomerase that was fixed on a solid surface was first developed in Japan by Takanashi. [7]