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Potassium ferrioxalate contains the iron(III) complex [Fe(C 2 O 4) 3] 3−. In chemistry, iron(III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron(III) chloride (FeCl 3). The adjective ferrous is used instead for iron(II) salts, containing the cation Fe 2+.
Iron(III) oxide is a product of the oxidation of iron. It can be prepared in the laboratory by electrolyzing a solution of sodium bicarbonate, an inert electrolyte, with an iron anode: 4 Fe + 3 O 2 + 2 H 2 O → 4 FeO(OH) The resulting hydrated iron(III) oxide, written here as FeO(OH), dehydrates around 200 °C. [18] [19] 2 FeO(OH) → Fe 2 O 3 ...
Iron(III) oxide-hydroxide or ferric oxyhydroxide [2] is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH). The compound is often encountered as one of its hydrates, FeO(OH) ·n H 2 O [rust]. The monohydrate FeO(OH) · H 2 O is often referred to as iron(III) hydroxide Fe(OH) 3, [3] hydrated iron oxide, yellow iron oxide ...
Iron(II) complexes are less stable than iron(III) complexes but the preference for O-donor ligands is less marked, so that for example [Fe(NH 3) 6] 2+ is known while [Fe(NH 3) 6] 3+ is not. They have a tendency to be oxidized to iron(III) but this can be moderated by low pH and the specific ligands used. [72]
Iron(III) chloride forms a 1:2 adduct with Lewis bases such as triphenylphosphine oxide; e.g., FeCl 3 (OP(C 6 H 5) 3) 2. The related 1:2 complex FeCl 3 (OEt 2) 2, where Et = C 2 H 5), has been crystallized from ether solution. [14] Iron(III) chloride also reacts with tetraethylammonium chloride to give the yellow salt of the tetrachloroferrate ...
The iron compounds produced on the largest scale in industry are iron(II) sulfate (FeSO 4 ·7H 2 O) and iron(III) chloride (FeCl 3). The former is one of the most readily available sources of iron(II), but is less stable to aerial oxidation than Mohr's salt ( (NH 4 ) 2 Fe(SO 4 ) 2 ·6H 2 O ).
Ferric oxalate, also known as iron(III) oxalate, refers to inorganic compounds with the formula Fe 2 (C 2 O 4) 3 (H 2 O) x but could also refer to salts of [Fe(C 2 O 4) 3] 3-. Fe 2 (C 2 O 4) 3 (H 2 O) x are coordination polymers with varying degrees of hydration.
structure of the cation called basic iron acetate as determined from X-ray crystallography [4] Basic iron acetate forms on treating aqueous solutions of iron(III) sources with acetate salts. It is slowly soluble in water and poorly soluble in acetic acid. [5] A typical precursor is freshly precipitated iron oxide/hydroxide, which is halide-free ...