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Unlike polyethylene, crystalline and amorphous regions differ only slightly in their density. However, the density of polyethylene can significantly change with fillers. [6]: 24 The Young's modulus of PP is between 1300 and 1800 N/mm². Polypropylene is normally tough and flexible, especially when copolymerized with ethylene.
For example, atactic polypropylene is usually amorphous and transparent while syndiotactic polypropylene, which has crystallinity ~50%, is opaque. [30] Crystallinity also affects dyeing of polymers: crystalline polymers are more difficult to stain than amorphous ones because the dye molecules penetrate through amorphous regions with greater ease.
Therefore, the polypropylene product generally did not require additional purification steps to remove the atactic or low crystalline fraction. This meant that the APP supply from polypropylene plants using standard first- and early second-generation Z-N catalysts decreased as commercial plants adopted the new catalysts.
The PP and PE components of a blend constitute the "crystalline phase", and the rubber and branched PE chains and PE/PP end groups gives the "amorphous phase". If PP and PE are the dominant component of a TPO blend then the rubber fraction will be dispersed into a continuous matrix of "crystalline" polypropylene.
All polymers (amorphous or semi-crystalline) go through glass transitions. The glass-transition temperature ( T g ) is a crucial physical parameter for polymer manufacturing, processing, and use. Below T g , molecular motions are frozen and polymers are brittle and glassy.
Many plastics are completely amorphous (without a highly ordered molecular structure), [20] including thermosets, polystyrene, and methyl methacrylate (PMMA). Crystalline plastics exhibit a pattern of more regularly spaced atoms, such as high-density polyethylene (HDPE), polybutylene terephthalate (PBT), and polyether ether ketone (PEEK ...
Polyamorphism is also an important area in pharmaceutical science. The amorphous form of a drug typically has much better aqueous solubility (compared to the analogous crystalline form) but the actual local structure in an amorphous pharmaceutical can be different, depending on the method used to form the amorphous phase.
Most clays are crystalline, but some clays or some parts of clay minerals are amorphous. [16] The clays of a soil are a mixture of the various types of clay, but one type predominates. [17] Typically there are four main groups of clay minerals: kaolinite, montmorillonite-smectite, illite, and chlorite. [18]