Search results
Results from the WOW.Com Content Network
The reaction of an organic substrate with phosgene is called phosgenation. [9] Phosgenation of diols give carbonates (R = H, alkyl, aryl), which can be either linear or cyclic: n HO−CR 2 −X−CR 2 −OH + n COCl 2 → [−O−CR 2 −X−CR 2 −O−C(=O)−] n + 2n HCl. An example is the reaction of phosgene with bisphenol A to form ...
Phosgene (carbonyl dichloride, Cl–CO–Cl) is a very toxic gas that is the dichloride of carbonic acid (HO–CO–OH). Both chlorine atoms in phosgene can undergo reactions analogous to the preceding reactions of acyl halides. Phosgene is used a reactant in the production of polycarbonate polymers, among other industrial applications.
It behaves like phosgene, to which it cracks thermally: OC(OCCl 3) 2 ⇌ 3 OCCl 2. Alcohols are converted to carbonates. Primary and secondary amines are converted to ureas and isocyanates. [6] [7] [9] [10] Triphosgene has been used to synthesize chlorides. [8] Some Alkyl chlorides are prepared by treating alcohols with a mixture of triphosgene ...
The sulfonium oxidations can be categorized into two groups: The methods discovered earliest rely on activated alcohols like alkyl tosylates (Kornblum oxidation) [2] or alkyl chloroformates (from reaction of alcohols with phosgene: Barton-Kornblum) [3] that react as electrophiles when treated with DMSO, liberating an oxygenated leaving group (e.g. OTs−).
Hydrolysis gives carbon dioxide and anthranilic acid. Alcoholysis proceeds similarly, affording the ester: C 6 H 4 C 2 O 3 NH + ROH → C 6 H 4 (CO 2 R)(NH 2) + CO 2. Amines also effect ring-opening.
Traces of a toxic, colorless gas were found at the headquarters of Sweden’s security agency where a suspected gas leak last week forced authorities to evacuate some 500 people from the facility ...
Isocyanates are usually produced from amines by phosgenation, i.e. treating with phosgene: RNH 2 + COCl 2 → RNCO + 2 HCl. These reactions proceed via the intermediacy of a carbamoyl chloride (RNHC(O)Cl). Owing to the hazardous nature of phosgene, the production of isocyanates requires special precautions. [1]
Denzel Washington revealed to Esquire magazine as part of a recent cover story that he is 10 years sober. He cut off alcohol at 60 years old after a 15-year drinking pattern that started in the ...