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Dimethyldioxirane (DMDO) is the organic compound with the formula (CH 3) 2 CO 2. [1] It is the dioxirane derived from acetone and can be viewed as the monomer of acetone peroxide.It is a powerful selective oxidizing agent that finds some use in organic synthesis.
Although DCM is a common solvent in organic chemistry laboratories and is commonly assumed to be inert, it does react with some amines and triazoles. [21] Tertiary amines can react with DCM to form quaternary chloromethyl chloride salts via the Menshutkin reaction. [22]
Print/export Download as PDF; Printable version; In other projects Wikidata item; ... 9.08 ε 0 at 20 °C Dipole moment, [3] 1.62 D Bond strength?
In organic chemistry, the Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol (−OH) is oxidized to an aldehyde (−CH=O) or ketone (>C=O) using oxalyl chloride, dimethyl sulfoxide (DMSO) and an organic base, such as triethylamine.
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A polar aprotic solvent is a solvent that lacks an acidic proton and is polar. Such solvents lack hydroxyl and amine groups. In contrast to protic solvents, these solvents do not serve as proton donors in hydrogen bonding, although they can be proton acceptors.
N,N′-Dicyclohexylcarbodiimide (DCC or DCCD) [1] is an organic compound with the chemical formula (C 6 H 11 N) 2 C. It is a waxy white solid with a sweet odor. Its primary use is to couple amino acids during artificial peptide synthesis.
In 1835, the French chemist Auguste Laurent recognised chloroform as CCl 2 • HCl (then written as C 8 Cl 8 • H 4 Cl 4) [a] in his paper on analysing some organohalides. Laurent also predicted a compound seemingly consisting of 2 parts dichlorocarbene which he named Chlorétherose (possibly Tetrachloroethylene, which was not known to exist at the time.) [8]