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NIR absorption bands are typically 10–100 times weaker than the corresponding fundamental mid-IR absorption band.) [4] The lower absorption allows NIR radiation to penetrate much further into a sample than mid infrared radiation. Near-infrared spectroscopy is, therefore, not a particularly sensitive technique, but it can be very useful in ...
The near-infrared (NIR) window (also known as optical window or therapeutic window) defines the range of wavelengths from 650 to 1350 nanometre (nm) where light has its maximum depth of penetration in tissue. [1] Within the NIR window, scattering is the most dominant light-tissue interaction, and therefore the propagating light becomes diffused ...
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
For any substance, the number density can be expressed in terms of its amount concentration c (in mol/m 3) as = where N A is the Avogadro constant. This is still true if the spatial dimension unit, metre, in both n and c is consistently replaced by any other spatial dimension unit, e.g. if n is in cm −3 and c is in mol/cm 3 , or if n is in L ...
1 Nm 3 of any gas (measured at 0 °C and 1 atmosphere of absolute pressure) equals 37.326 scf of that gas (measured at 60 °F and 1 atmosphere of absolute pressure). 1 kmol of any ideal gas equals 22.414 Nm 3 of that gas at 0 °C and 1 atmosphere of absolute pressure ... and 1 lbmol of any ideal gas equals 379.482 scf of that gas at 60 °F and ...
where p A is the partial pressure of A over the surface, [S] is the concentration of free sites in number/m 2, [A ad] is the surface concentration of A in molecules/m 2 (concentration of occupied sites), and k ad and k d are constants of forward adsorption reaction and backward desorption reaction in the above reactions.
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
P = pressure V = volume n = number of moles R = universal gas constant T = temperature. The ideal gas equation of state can be arranged to give: = / or = / The following partial derivatives are obtained from the above equation of state: