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The face-centered cubic lattice is closely related to the hexagonal close packed (hcp) system, where two systems differ only in the relative placements of their hexagonal layers. The [111] plane of a face-centered cubic lattice is a hexagonal grid.
Both arrangements produce a face-centered cubic lattice – with different orientation to the ground. Hexagonal close-packing would result in a six-sided pyramid with a hexagonal base. Collections of snowballs arranged in pyramid shape. The front pyramid is hexagonal close-packed and rear is face-centered cubic.
For a face-centered cubic unit cell, the number of atoms is four. A line can be drawn from the top corner of a cube diagonally to the bottom corner on the same side of the cube, which is equal to 4r. Using geometry, and the side length, a can be related to r as: =.
BCC is body centered cubic and FCC is face-centered cubic. Iron-carbon eutectic phase diagram, showing various forms of Fe x C y substances. Iron allotropes, showing the differences in structure. The alpha iron (α-Fe) is a body-centered cubic (BCC) and the gamma iron (γ-Fe) is a face-centered cubic (FCC).
This type of structural arrangement is known as cubic close packing (ccp). The unit cell of a ccp arrangement of atoms is the face-centered cubic (fcc) unit cell. This is not immediately obvious as the closely packed layers are parallel to the {111} planes of the fcc unit cell. There are four different orientations of the close-packed layers.
The atomic packing factor of the diamond cubic structure (the proportion of space that would be filled by spheres that are centered on the vertices of the structure and are as large as possible without overlapping) is , [3] significantly smaller (indicating a less dense structure) than the packing factors for the face-centered and body-centered ...
Octahedral (red) and tetrahedral (blue) interstitial symmetry polyhedra in a face-centered cubic lattice. The actual interstitial atom would ideally be in the middle of one of the polyhedra. A close packed unit cell, both face-centered cubic and hexagonal close packed, can form two different shaped holes.
In another example, iron transforms from a body-centered cubic (bcc) structure called ferrite to a face-centered cubic (fcc) structure called austenite when it is heated. [14] The fcc structure is a close-packed structure unlike the bcc structure; thus the volume of the iron decreases when this transformation occurs.