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Mesotrione is a selective herbicide used mainly in maize crops. [1] It is a synthetic compound inspired by the natural substance leptospermone found in the bottlebrush tree Callistemon citrinus . It inhibits the enzyme 4-hydroxyphenylpyruvate dioxygenase (HPPD) [ 3 ] and is sold under brand names including Callisto and Tenacity.
Mesotrione was introduced in 2002 and like sulcotrione is a triketone, so it is effective on the same weeds and crops, but is more potent, making it more useful in mixes with other herbicides - an important factor for fully controlling weeds and preventing the development of resistance. It has become the biggest selling member of the HPPD class ...
Halosulfuron-methyl is a sulfonylurea post-emergence herbicide used to control some annual and perennial broad-leaved weeds and sedges (such as nutsedge/nutgrass) in a range of crops (particularly rice), established landscape woody ornamentals and turfgrass.
The so-called cyclohexanedione herbicides, which are used against grasses, include the following commercial products cycloxydim, clethodim, tralkoxydim, butroxydim, sethoxydim, profoxydim, and mesotrione. [26] Knowing about herbicide chemical family grouping serves as a short-term strategy for managing resistance to site of action. [27]
In the mid-1980s, scientists at Stauffer Chemical Company published patents to benzoyl-substituted cyclohexanediones which led to their product mesotrione. [3] This encouraged workers at Rhône-Poulenc to expand their own research into molecules with the same mode of action as these 4-hydroxyphenylpyruvate dioxygenase inhibitors .
Leptospermone can be synthesized from phloroglucinol by a reaction with 3-methylbutanenitrile (isovaleronitrile) in the presence of a zinc chloride catalyst. . Phloroisovalerone imine is produced which is then alkylated with iodomethane after initial treatment with sodium ethoxide and methanol to produce an intermediate which is treated with aqueous hydrochloric acid resulting in ...
“It’s different every single day,” said DJ Schoeff, an officer in Indiana and vice president of NASRO, while sitting in the back of one of the conference’s basic training courses. The SROs in his school greet the kids in the morning, which he said helps students create a trusting relationship with police.
It is a highly aggressive invasive species, crowding out most other grasses and invading other habitats, and has become a hard-to-eradicate weed in some areas (it can be controlled somewhat with Triclopyr, Mesotrione, Fluazifop-P-butyl, and Glyphosate). [18] [19] This weedy nature leads some gardeners to give it the name of "devil grass ...
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