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  2. Sodium selenide - Wikipedia

    en.wikipedia.org/wiki/Sodium_selenide

    Sodium selenide is an inorganic compound of sodium and selenium with the chemical formula Na 2 Se. Preparation. This colourless solid is prepared by the reaction of ...

  3. Selenide - Wikipedia

    en.wikipedia.org/wiki/Selenide

    Sample of cadmium selenide, a pigment. The parent inorganic selenide is hydrogen selenide (H 2 Se). It is a colorless, malodorous, toxic gas. It dissolves in aqueous solution, to give the hydrogenselenide or biselenide ion HSe −. At higher pH, selenide forms. Solutions of hydrogen selenide and selenide are oxidized by air to give elemental ...

  4. Organoselenium chemistry - Wikipedia

    en.wikipedia.org/wiki/Organoselenium_chemistry

    In presence of a β-hydrogen, a selenide will give an elimination reaction after oxidation, to leave behind an alkene and a SeO-selenoperoxol. The SeO-selenoperoxol is highly reactive and is not isolated as such. In the elimination reaction, all five participating reaction centers are coplanar and, therefore, the reaction stereochemistry is syn.

  5. Selenium compounds - Wikipedia

    en.wikipedia.org/wiki/Selenium_compounds

    The selenide dianion Se 2− forms a variety of compounds, including the minerals from which selenium is obtained commercially. Illustrative selenides include mercury selenide (HgSe), lead selenide (PbSe), zinc selenide (ZnSe), and copper indium gallium diselenide (Cu(Ga,In)Se 2 ).

  6. Selenoxide elimination - Wikipedia

    en.wikipedia.org/wiki/Selenoxide_elimination

    Sodium benzeneselenolate; Trimethylsilyl phenyl selenide; The most common oxidizing agent employed is hydrogen peroxide (H 2 O 2). [9] It is sometimes used in excess, to overcome catalytic decomposition of H 2 O 2 by selenium; however, undesired oxidation of starting material has been observed under these conditions.

  7. Benzeneselenol - Wikipedia

    en.wikipedia.org/wiki/Benzeneselenol

    More so than thiophenol, benzeneselenol is easily oxidized by air. The facility of this reaction reflects the weakness of the Se-H bond, bond dissociation energy of which is estimated to be between 67 and 74 kcal/mol. [1] In contrast, the S-H BDE for thiophenol is near 80 kcal/mol. [3] The product is diphenyl diselenide as shown in this idealized equation:

  8. Sodium hydroselenide - Wikipedia

    en.wikipedia.org/wiki/Sodium_hydroselenide

    Sodium hydroselenide is an inorganic compound with the chemical formula Na Se H. It is a salt of hydrogen selenide. It consist of sodium cations Na + and hydroselenide anions − SeH. Each unit consists of one sodium, one selenium, and one hydrogen atom. Sodium hydroselenide is a selenium analog of sodium hydroxide NaOH.

  9. Phenylsodium - Wikipedia

    en.wikipedia.org/wiki/Phenylsodium

    The Shorigen reaction is also used in the generation of phenylsodium, where an alkyl sodium compound is treated with benzene: [3] RNa + C 6 H 6 → RH + C 6 H 5 Na. The method can also result in the addition of a second sodium. This dimetallation occurs in the meta and para positions. The use of certain alkyl sodium compounds such as n-amyl ...