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A superabsorbent polymer (SAP) (also called slush powder) is a water-absorbing hydrophilic homopolymers or copolymers [1] that can absorb and retain extremely large amounts of a liquid relative to its own mass. [2] Water-absorbing polymers, which are classified as hydrogels when mixed, [3] absorb aqueous solutions through hydrogen bonding with ...
Another application of polymer solutions includes the manufacture of fibers by wet or dry spinning or plastic films. Disadvantages of solution polymerization are decrease of monomer and initiator concentration leading to reduction of reaction rate, lower volume utilization of reactor, additional cost of the process related to solvent recycling ...
It is a common observation that when oil and water are poured into the same container, they separate into two phases or layers, because they are immiscible.In general, aqueous (or water-based) solutions, being polar, are immiscible with non-polar organic solvents (cooking oil, chloroform, toluene, hexane etc.) and form a two-phase system.
Most step-growth polymers are also classified as condensation polymers, since a small molecule such as water is lost when the polymer chain is lengthened. For example, polyester chains grow by reaction of alcohol and carboxylic acid groups to form ester links with loss of water.
The most commonly used interfacial polymerization methods fall into 3 broad types of interfaces: liquid-solid interfaces, liquid-liquid interfaces, and liquid-in-liquid emulsion interfaces. [1] In the liquid-liquid and liquid-in-liquid emulsion interfaces, either one or both liquid phases may contain monomers.
In polymer chemistry, suspension polymerization is a heterogeneous radical polymerization process that uses mechanical agitation to mix a monomer or mixture of monomers in a liquid phase, such as water, while the monomers polymerize, forming spheres of polymer. [2] The monomer droplets (size of the order 10-1000 μm) are suspended in the liquid ...
However, only solid→liquid and liquid→solid phase changes are practical for PCMs. Although liquid–gas transitions have a higher heat of transformation than solid–liquid transitions, liquid→gas phase changes are impractical for thermal storage because large volumes or high pressures are required to store the materials in their gas phase.
Super-absorbent polymers (SAP) similar to sodium polyacrylate were developed in the 1960s by the U.S. Department of Agriculture. [3] Before the development of these substances, the best water absorbing materials were cellulosic or fiber-based like tissue paper, sponge, cotton, or fluff pulp.