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  2. Fluorination by sulfur tetrafluoride - Wikipedia

    en.wikipedia.org/wiki/Fluorination_by_sulfur...

    Reaction times tend to be on the order of hours and yields are moderate. [7] Fluorination of lactones can provide heterocyclic fluorides, although ring opening has been observed for γ-butyrolactone. The six-membered lactide does not experience ring opening. [8] Fluorination opens epoxides to give either geminal or vicinal difluorides in most ...

  3. Sulfur tetrafluoride - Wikipedia

    en.wikipedia.org/wiki/Sulfur_tetrafluoride

    It is a colorless corrosive gas that releases dangerous hydrogen fluoride gas upon exposure to water or moisture. Sulfur tetrafluoride is a useful reagent for the preparation of organofluorine compounds, [3] some of which are important in the pharmaceutical and specialty chemical industries.

  4. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    Shape of water molecule showing that the real bond angle 104.5° deviates from the ideal sp 3 angle of 109.5°. In chemistry, Bent's rule describes and explains the relationship between the orbital hybridization and the electronegativities of substituents. [1] [2] The rule was stated by Henry A. Bent as follows: [2]

  5. Orbital hybridisation - Wikipedia

    en.wikipedia.org/wiki/Orbital_hybridisation

    Chemist Linus Pauling first developed the hybridisation theory in 1931 to explain the structure of simple molecules such as methane (CH 4) using atomic orbitals. [2] Pauling pointed out that a carbon atom forms four bonds by using one s and three p orbitals, so that "it might be inferred" that a carbon atom would form three bonds at right angles (using p orbitals) and a fourth weaker bond ...

  6. Difluorodisulfanedifluoride - Wikipedia

    en.wikipedia.org/wiki/Difluorodisulfanedifluoride

    SF 3 SCl can be removed from this mixture in a reaction with mercury. [8] Separation of the sulfur fluorides can be achieved by low temperature distillation. SF 3 SF distills just above -50 °C. [9] SF 3 SF is also made in small amounts by reacting sulfur with silver fluoride, or photolysis of disulfur difluoride and SSF 2. [8]

  7. 5 Tips to Make the Best Alcohol-Free Cocktails, According to ...

    www.aol.com/5-tips-best-alcohol-free-182900197.html

    Unlike traditional cocktails made that use a spirit as a base, most nonalcoholic drinks are water-based or contain a high quantity of water through ingredients like fruit juices or teas.

  8. WNBA Team Owner Catches Heat For Criticizing Time’s Caitlin ...

    www.aol.com/wnba-team-owner-catches-heat...

    The Mystics co-owner’s remarks about the cover garnered backlash from the sports world. Women’s tennis legend Chris Evert, in a reply on X, wrote that Clark “deserves this award because of ...

  9. Fluorination with aminosulfuranes - Wikipedia

    en.wikipedia.org/wiki/Fluorination_with_amino...

    Fluorination with aminosulfuranes is a chemical reaction that transforms oxidized organic compounds into organofluorine compounds.Aminosulfuranes selectively exchange hydroxyl groups for fluorine, but are also capable of converting carbonyl groups, halides, silyl ethers, and other functionality into organofluorides.