Search results
Results from the WOW.Com Content Network
Fullerenes had been predicted for some time, but only after their accidental synthesis in 1985 were they detected in nature [3] [4] and outer space. [ 5 ] [ 6 ] The discovery of fullerenes greatly expanded the number of known allotropes of carbon, which had previously been limited to graphite, diamond , and amorphous carbon such as soot and ...
Whereas buckyballs are spherical in shape, a nanotube is cylindrical, with at least one end typically capped with a hemisphere of the buckyball structure. Their name is derived from their size, since the diameter of a nanotube is on the order of a few nanometers (approximately 50,000 times smaller than the width of a human hair), while they can ...
It is a cage-like fused-ring structure which resembles a rugby ball, made of 25 hexagons and 12 pentagons, with a carbon atom at the vertices of each polygon and a bond along each polygon edge. A related fullerene molecule, named buckminsterfullerene (or C 60 fullerene) consists of 60 carbon atoms.
These endohedral fullerenes are usually synthesized by doping in the metal atoms in an arc reactor or by laser evaporation. These methods gives low yields of endohedral fullerenes, and a better method involves the opening of the cage, packing in the atoms or molecules, and closing the opening using certain organic reactions. This method ...
The names fullerene and buckyball are given after Richard Buckminster Fuller, popularizer of geodesic domes, which resemble the structure of fullerenes. The buckyballs are fairly large molecules formed completely of carbon bonded trigonally, forming spheroids (the best-known and simplest is the soccerball-shaped C 60 buckminsterfullerene ). [ 31 ]
Besides unfilled fullerenes, endohedral metallofullerenes develop with different cage sizes like La@C 60 or La@C 82 and as different isomer cages. Aside from the dominant presence of mono-metal cages, numerous di-metal endohedral complexes and the tri-metal carbide fullerenes like Sc 3 C 2 @C 80 were also isolated. In 1999 a discovery drew ...
Fullerenes can react with halogens. The preferred pattern for addition C 60 is calculated to be 1,9- for small groups and 1,7- for bulky groups. C 60 F 60 is a possible structure. C 60 reacts with Cl 2 gas at 250 °C to a material with average composition C 60 Cl 24, although only C 60 can be detected by mass spectrometry. [14]
A network solid or covalent network solid (also called atomic crystalline solids or giant covalent structures) [1] [2] is a chemical compound (or element) in which the atoms are bonded by covalent bonds in a continuous network extending throughout the material.