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The most common method of eliminating the liquid junction potential is to place a salt bridge consisting of a saturated solution of potassium chloride (KCl) and ammonium nitrate (NH 4 NO 3) with lithium acetate (CH 3 COOLi) between the two solutions constituting the junction. When such a bridge is used, the ions in the bridge are present in ...
The current entering any junction is equal to the current leaving that junction. i 2 + i 3 = i 1 + i 4. This law, also called Kirchhoff's first law, or Kirchhoff's junction rule, states that, for any node (junction) in an electrical circuit, the sum of currents flowing into that node is equal to the sum of currents flowing out of that node; or equivalently:
Nodal analysis is essentially a systematic application of Kirchhoff's current law (KCL) for circuit analysis. Similarly, mesh analysis is a systematic application of Kirchhoff's voltage law (KVL). Nodal analysis writes an equation at each electrical node specifying that the branch currents incident at a node must sum to zero (using KCL). The ...
A theorem in calculus, useful in analytic solutions of problems in electromagnetism. Kilovolt-ampere A unit of apparent power. Kirchhoff's circuit laws The observation that the sum of the currents at any node of a circuit must be zero, and the sum of the voltage differences around any loop must be zero; often abbreviated "KCL" and "KVL" in ...
Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt-like taste. Potassium chloride can be obtained from ancient dried lake deposits. [7]
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
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This gives the SCE a potential of +0.248 V vs. SHE at 20 °C and +0.244 V vs. SHE at 25 °C, [1] but slightly higher when the chloride solution is less than saturated. For example, a 3.5M KCl electrolyte solution has an increased reference potential of +0.250 V vs. SHE at 25°C while a 1 M solution has a +0.283 V potential at the same temperature.