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The 2,6 and 3,5 isomers do not form acceptably from toluene or chlorotoluenes, so these isomers are prepared by indirect methods. For example, 2,6-dichlorotoluene can be prepared by chlorination of 4-toluenesulfonyl chloride followed by desulfonation .
A laboratory route to 2- and 4-chlorotoluene proceeds from 2- and 4-toluidines (i.e. 2- and 4-aminotoluene). These compounds are diazotized followed by treatment with cuprous chloride. [1] Industrially, the diazonium method is reserved for 3-chlorotoluene. The industrial route to 2- and 4-chlorotoluene entails direct reaction of toluene with ...
2,4-Dichlorobenzoic acid is an organic compound with the formula C 6 H 3 Cl 2 CO 2 H. It is one of more important of several isomers of dichlorobenzoic acid. It can be prepared by oxidation of 2,4-dichlorotoluene. [2] The coenzyme A thioester of 2,4-dichlorobenzoic acid is the substrate for 2,4-dichlorobenzoyl reductase.
3,4-Dichlorophenol 3,5-Dichlorophenol Dichlorophenols are used as intermediates in the manufacture of more complex chemical compounds, including the common herbicide 2,4-dichlorophenoxyacetic acid (2,4-D).
C 7 H 6 Cl 2 Molar mass: 161.03 g/mol Appearance Colorless liquid Density: 1.254 g/cm 3, liquid Melting point: −17 to −15 °C (1 to 5 °F; 256 to 258 K) Boiling point: 205 °C (401 °F; 478 K) (82 °C at 10 mmHg)
2,4-Dichlorophenol (2,4-DCP) is a chlorinated derivative of phenol with the molecular formula Cl 2 C 6 H 3 OH. It is a white solid that is mildly acidic (pK a = 7.9). It is produced on a large scale as a precursor to the herbicide 2,4-dichlorophenoxyacetic acid (2,4-D).
R-dichlorprop (dichlorprop-p). Dichlorprop possesses a single asymmetric carbon and is therefore a chiral molecule, however only the R-isomer is active as an herbicide.When dichlorprop was first marketed in the 1960s, it was sold as racemic mixture of stereoisomers, but since then advances in asymmetric synthesis have made possible the production of the enantiopure compound.
2,4-Dinitrotoluene (DNT) or dinitro is an organic compound with the formula C 7 H 6 N 2 O 4. This pale yellow crystalline solid is well known as a precursor to trinitrotoluene (TNT) but is mainly produced as a precursor to toluene diisocyanate .