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Molybdenum hexacarbonyl is a popular reagent in academic research. [6]One or more CO ligands can be displaced by other ligands. [7] Mo(CO) 6, [Mo(CO) 3 (MeCN) 3], and related derivatives are employed as catalysts in organic synthesis for example, alkyne metathesis and the Pauson–Khand reaction.
Unlike many other cofactors, molybdenum cofactor (Moco) cannot be taken up as a nutrient. The cofactor thus requires de novo biosynthesis.Molybdenum cofactor biosynthesis occurs in four steps: (i) the radical-mediated cyclization of nucleotide, guanosine triphosphate (GTP), to (8S)‑3',8‐cyclo‑7,8‑dihydroguanosine 5'‑triphosphate (3',8‑cH 2 GTP), (ii) the formation of cyclic ...
Chemical formula Synonyms CAS number C 10 H 16 N 2 O 8: Ethylenediaminetetraacetic acid (EDTA): 6381–92–6 C 12 H 22 O 11: sucrose: 57–50–1 C 18 H 29 O 3 S: sodium dodecyl benzenesulfonate: 2155–30–0
Screenshot of the CAS Common Chemistry database with information about caffeine ().. A CAS Registry Number [1] (also referred to as CAS RN [2] or informally CAS Number) is a unique identification number, assigned by the Chemical Abstracts Service (CAS) in the US to every chemical substance described in the open scientific literature, in order to index the substance in the CAS Registry.
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Mo 2 (O 2 CCH 3) 4 is prepared by treating molybdenum hexacarbonyl (Mo(CO) 6) with acetic acid.The process strips CO ligands from the hexacarbonyl and results in the oxidation of Mo(0) to Mo(II).
Transition state for MoOPH alpha-hydroxylation. Due to MoOPH's steric bulk, preferential attack at the O–O bond occurs from the less hindered enolate face in the absence of stereoelectronic factors.