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The chloralkali process (also chlor-alkali and chlor alkali) is an industrial process for the electrolysis of sodium chloride (NaCl) solutions. It is the technology used to produce chlorine and sodium hydroxide (caustic soda), [ 1 ] which are commodity chemicals required by industry.
Another earlier process to produce chlorine was to heat brine with acid and manganese dioxide. 2 NaCl + 2H 2 SO 4 + MnO 2 → Na 2 SO 4 + MnSO 4 + 2 H 2 O + Cl 2. Using this process, chemist Carl Wilhelm Scheele was the first to isolate chlorine in a laboratory. The manganese can be recovered by the Weldon process. [11]
The chlorine gas that results vents at the top of the outside cells where it is collected as a byproduct of the process. The reaction at the mercury cathode in the outer cells is Na + + e − → Na (amalgam) The sodium metal formed by this reaction dissolves in the mercury to form an amalgam. The mercury conducts the current from the outside ...
The chlor-alkali industry is a major consumer of the world's energy budget. This process converts concentrated sodium chloride solutions into chlorine and sodium hydroxide, which are used to make many other materials and chemicals. The process involves two parallel reactions: 2 Cl − → Cl 2 + 2 e − 2 H 2 O + 2 e − → H 2 + 2 OH −
The Deacon process, invented by Henry Deacon, is a process used during the manufacture of alkalis (the initial end product was sodium carbonate) by the Leblanc process. Hydrogen chloride gas was converted to chlorine gas, which was then used to manufacture a commercially valuable bleaching powder , and at the same time the emission of waste ...
After the war, the Olins acquired the Mathieson Chemical Corporation—also founded in 1892. [8] [9] [10] Long before its association with Olin, Mathieson Alkali Works began business in Saltville, Virginia, and a year later acquired its neighbor, the Holston Salt and Plaster Corp. Saltville became a quintessential company town, where they produced chlorine and caustic soda, and in the process ...
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This article needs to be updated.The reason given is: This is a historical article, primarily based on the Encyclopædia Britannica Eleventh Edition.Information on more recent methods should be integrated from Sodium hydroxide#Production, Chloralkali process, and others, to make this a workable overview of all the historical and modern methods.