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In chemistry, orthosilicate is the anion SiO 4− 4, or any of its salts and esters. It is one of the silicate anions. It is occasionally called the silicon tetroxide anion or group. [1] Orthosilicate salts, like sodium orthosilicate, are stable, and occur widely in nature as silicate minerals, being the defining feature of the nesosilicates. [2]
Structure of the orthosilicate anion SiO 4− 4. A silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula [SiO (4-2x)− 4−x] n, where 0 ≤ x < 2. The family includes orthosilicate SiO 4− 4 (x = 0), metasilicate SiO 2− 3 (x = 1), and pyrosilicate Si 2 O 6− 7 (x = 0.5 ...
Although rarely observed, it is the key compound of silica and silicates and the precursor to other silicic acids [H 2x SiO x+2] n. Silicic acids play important roles in biomineralization and technology. [2] [3] [4] It is the parent acid of the orthosilicate anion SiO 4− 4.
Sodium silicate is a generic name for chemical compounds with the formula Na 2x Si y O 2y+x or (Na 2 O) x · (SiO 2) y, such as sodium metasilicate (Na 2 SiO 3), sodium orthosilicate (Na 4 SiO 4), and sodium pyrosilicate (Na 6 Si 2 O 7). The anions are often polymeric. These compounds are generally colorless transparent solids or white powders ...
A silicate mineral is generally an inorganic compound consisting of subunits with the formula [SiO 2+n] 2n−. Although depicted as such, the description of silicates as anions is a simplification. Balancing the charges of the silicate anions are metal cations, M x+. Typical cations are Mg 2+, Fe 2+, and Na +. The Si-O-M linkage between the ...
Calcium silicate neutralizes active acidity in AMD systems by removing free hydrogen ions from the bulk solution, thereby increasing pH. As its silicate anion captures H + ions (raising the pH), it forms monosilicic acid (H 4 SiO 4), a neutral solute. Monosilicic acid remains in the bulk solution to play other important roles in correcting the ...
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The 2nd group of anions consist of Cl −, Br −, I −, NO − 3 and C 2 O 2− 4. The group reagent for Group 2 anion is concentrated sulfuric acid (H 2 SO 4). After addition of the acid, chlorides, bromides and iodides will form precipitates with silver nitrate. The precipitates are white, pale yellow, and yellow, respectively.