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Chloranil is a quinone with the molecular formula C 6 Cl 4 O 2. Also known as tetrachloro-1,4-benzoquinone, it is a yellow solid. Also known as tetrachloro-1,4-benzoquinone, it is a yellow solid. Like the parent benzoquinone, chloranil is a planar molecule [ 2 ] that functions as a mild oxidant.
It is a red-orange solid. The compound is obtained by hydrolysis of chloranil: C 6 Cl 4 O 2 + 2 H 2 O → C 6 Cl 2 O 2 (OH) 2 + 2 HCl. It is centrosymmetric, planar molecule. It also crystallizes as a dihydrate. [2] Chloranilic acid is a noteworthy hydroxyquinone that is somewhat acidic owing to the presence of the two chloride substituents.
Chlorothalonil is commercially available in many different formulations and delivery methods. It is applied as a dust, dry or water-soluble grains, a wettable powder, a liquid spray, a fog, and a dip. It may be applied by hand, by ground sprayer, or by aircraft. [2]
Relative to benzoquinone, more strongly oxidizing quinones include chloranil and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (also known as DDQ). [6] The oxidizing power of quinones is enhanced by the presence of acids. [7] In acidic conditions, quinone undergoes two-electron and two-proton reduction to hydroquinone.
Hypochlorous acid is a natural molecule in the body but can also be used in skincare. Experts share how it’s used and why it’s the latest buzzy ingredient.
Synthesis of DDQ involves cyanation of chloranil. J. Thiele and F. Günther first reported a 6-step preparation in 1906. [7] The substance did not receive interest until its potential as a dehydrogenation agent was discovered. A single-step chlorination from 2,3-dicyanohydroquinone was reported in 1965. [8]
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