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Acetonitrile is less basic than DMSO, and, so, in general, acids are weaker and bases are stronger in this solvent. Some pK a values at 25 °C for acetonitrile (ACN) [37] [38] [39] and dimethyl sulfoxide (DMSO). [40] are shown in the following tables. Values for water are included for comparison.
The higher the proton affinity, the stronger the base and the weaker the conjugate acid in the gas phase.The (reportedly) strongest known base is the ortho-diethynylbenzene dianion (E pa = 1843 kJ/mol), [3] followed by the methanide anion (E pa = 1743 kJ/mol) and the hydride ion (E pa = 1675 kJ/mol), [4] making methane the weakest proton acid [5] in the gas phase, followed by dihydrogen.
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Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
Note that the rusting of iron is a reaction between iron and oxygen [95] that is dissolved in water, not between iron and water. Water can be oxidized to emit oxygen gas, but very few oxidants react with water even if their reduction potential is greater than the potential of O 2 /H 2 O. Almost all such reactions require a catalyst. [96]
For instance, hydrogen fluoride, whether dissolved in water (= 3.2) or DMSO (= 15), has values indicating that it undergoes incomplete dissociation in these solvents, making it a weak acid. However, as the rigorously dried, neat acidic medium, hydrogen fluoride has an H 0 {\displaystyle H_{0}} value of –15, [ 1 ] making it a more strongly ...
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In pure water, there is an equal number of hydroxide and H + ions, so it is a neutral solution. At 25 °C (77 °F), pure water has a pH of 7 and a pOH of 7 (this varies when the temperature changes: see self-ionization of water). A pH value less than 7 indicates an acidic solution, and a pH value more than 7 indicates a basic solution. [7]