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Specific volume is commonly applied to: Molar volume; Volume (thermodynamics) Partial molar volume; Imagine a variable-volume, airtight chamber containing a certain number of atoms of oxygen gas. Consider the following four examples: If the chamber is made smaller without allowing gas in or out, the density increases and the specific volume ...
In thermodynamics, the volume of a system is an important extensive parameter for describing its thermodynamic state. The specific volume, an intensive property, is the system's volume per unit mass. Volume is a function of state and is interdependent with other thermodynamic properties such as pressure and temperature.
Redlich noted that, although physical properties and especially thermodynamic properties are most conveniently defined as either intensive or extensive, these two categories are not all-inclusive and some well-defined concepts like the square-root of a volume conform to neither definition. [1]
Heat capacity (constant volume) C v: J/K Specific heat capacity (constant volume) c v: J/(kg·K) Helmholtz free energy: A, F: J Helmholtz free entropy: Φ: J/K Internal energy: U: J Specific internal energy: u: J/kg Internal pressure: π T: Pa Mass: m: kg Particle number: N i – Chemical potential μ i: Pressure: p: Pa Volume V: Temperature: T ...
Specific heat capacity (isobaric) ... where k B is the Boltzmann constant, and Ω denotes the volume of macrostate in the phase space or otherwise called ...
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
The above expression for vapor quality can be expressed as: = where is equal to either specific enthalpy, specific entropy, specific volume or specific internal energy, is the value of the specific property of saturated liquid state and is the value of the specific property of the substance in dome zone, which we can find both liquid and vapor .
Maxwell relations in thermodynamics are critical because they provide a means of simply measuring the change in properties of pressure, temperature, and specific volume, to determine a change in entropy. Entropy cannot be measured directly.