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Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula AlCl 3.It forms a hexahydrate with the formula [Al(H 2 O) 6]Cl 3, containing six water molecules of hydration.
The reaction proceeds through generation of an acylium center. The reaction is completed by deprotonation of the arenium ion by AlCl 4 −, regenerating the AlCl 3 catalyst. However, in contrast to the truly catalytic alkylation reaction, the formed ketone is a moderate Lewis base, which forms a complex with the strong Lewis acid aluminum ...
Two common modes of Lewis acid catalysis in reactions with polar mechanisms. In reactions with polar mechanisms, Lewis acid catalysis often involves binding of the catalyst to Lewis basic heteroatoms and withdrawing electron density, which in turn facilitates heterolytic bond cleavage (in the case of Friedel-Crafts reaction) or directly activates the substrate toward nucleophilic attack (in ...
In hot concentrated hydrochloric acid, aluminium reacts with water with evolution of hydrogen, and in aqueous sodium hydroxide or potassium hydroxide at room temperature to form aluminates—protective passivation under these conditions is negligible. [9] The reaction with aqueous alkali is often written: [2] Al + NaOH + H 2 O → NaAlO 2 ...
In water purification, this compound is preferred in some cases because of its high charge, which makes it more effective at destabilizing and removing suspended materials than other aluminium salts such as aluminium sulfate, aluminium chloride and various forms of polyaluminium chloride (PAC) and polyaluminium chlorosulfate, in which the ...
The reaction of an acid in water solvent is often described as a dissociation + + where HA is a proton acid such as acetic acid, CH 3 COOH. The double arrow means that this is an equilibrium process, with dissociation and recombination occurring at the same time.
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Phase behavior Triple point? K (? °C), ? Pa Critical point: 625.7 K (352.6 °C), 2.600 MPa Std enthalpy change of fusionΔ fus H o? kJ/mol Std entropy change