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The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode (SHE), at: Temperature 298.15 K (25.00 °C; 77.00 °F); Effective concentration (activity) 1 mol/L for each aqueous or amalgamated (mercury-alloyed) species; Unit activity for each solvent and pure solid or liquid species; and
The reactivity series is sometimes quoted in the strict reverse order of standard electrode potentials, when it is also known as the "electrochemical series". [8] The following list includes the metallic elements of the first six periods. It is mostly based on tables provided by NIST.
The values below are standard apparent reduction potentials (E°') for electro-biochemical half-reactions measured at 25 °C, 1 atmosphere and a pH of 7 in aqueous solution. [ 1 ] [ 2 ] The actual physiological potential depends on the ratio of the reduced ( Red ) and oxidized ( Ox ) forms according to the Nernst equation and the thermal voltage .
The electrode potentials are independent of the number of electrons transferred —they are expressed in volts, which measure energy per electron transferred—and so the two electrode potentials can be simply combined to give the overall cell potential even if different numbers of electrons are involved in the two electrode reactions.
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To avoid possible ambiguities, the electrode potential thus defined can also be referred to as Gibbs–Stockholm electrode potential. In both conventions, the standard hydrogen electrode is defined to have a potential of 0 V. Both conventions also agree on the sign of E for a half-cell reaction when it is written as a reduction.
A reference electrode is an electrode that has a stable and well-known electrode potential. The overall chemical reaction taking place in a cell is made up of two independent half-reactions , which describe chemical changes at the two electrodes.