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Fluorine is a chemical element; it has symbol F and atomic number 9. It is the lightest halogen [note 1] and exists at standard conditions as pale yellow diatomic gas. Fluorine is extremely reactive as it reacts with all other elements except for the light inert gases. It is highly toxic.
Reactions with elemental fluorine are often sudden or explosive. Many substances that are generally regarded as unreactive, such as powdered steel, glass fragments, and asbestos fibers, are readily consumed by cold fluorine gas. Wood and even water burn with flames when subjected to a jet of fluorine, without the need for a spark. [12] [13]
Out of the four stable halogens, only fluorine and chlorine have reduction potentials higher than that of oxygen, allowing them to form hydrofluoric acid and hydrochloric acid directly through reaction with water. [17] The reaction of fluorine with water is especially hazardous, as an addition of fluorine gas to cold water will produce ...
Fluorine, in the form of fluoride, is considered to be a micronutrient for human health, necessary to prevent dental cavities, and to promote healthy bone growth. [28] The tea plant (Camellia sinensis L.) is a known accumulator of fluorine compounds, released upon forming infusions such as the common beverage. The fluorine compounds decompose ...
This reaction is catalyzed by water. [2] It was isolated in the pure form by passing F 2 gas over ice at −40 °C, rapidly collecting the HOF gas away from the ice, and condensing it: [2] F 2 + H 2 O → HOF + HF. The compound has been characterized in the solid phase by X-ray crystallography [1] as a bent molecule with an angle of 101°.
Fluorine-18 is usually produced by irradiation of 18 O-enriched water (H 2 18 O) with high-energy (about 18 MeV) protons prepared in a cyclotron or a linear accelerator, yielding an aqueous solution of 18 F fluoride. This solution is then used for rapid synthesis of a labeled molecule, often with the fluorine atom replacing a hydroxyl group.
Fluorine compounds are highly amenable to nuclear magnetic resonance (NMR), because fluorine-19 has a nuclear spin of 1 ⁄ 2, a high nuclear magnetic moment, and a high magnetogyric ratio. Fluorine compounds typically have a fast NMR relaxation , which enables the use of fast averaging to obtain a signal-to-noise ratio similar to hydrogen-1 ...
Usually, the reaction 2 HF(g) + 2 e − → 2 F − + H 2 (g). is set at zero volts. This reaction proves convenient in a laboratory setting and can be used to set the salt to zero through bubbling a 1:1 mixture of hydrogen fluoride and hydrogen through the salt. Occasionally the reaction: NiF 2 (d) + 2 e − → Ni(c) + 2 F −. is used as a ...