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The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
The terms sec and tert are considered obsolete and should only be used for unsubstituted sec-butoxy, sec-butyl [26] [27] or tert-butyl groups. [ 28 ] [ 27 ] There are various spellings such as "sec-butyl", "s-butyl", "sBu" or "bus" which are also considered obsolete.
Adjustable beds or electric adjustable bed sizes differ from the standard bed size. The length of these beds differ from a standard size due to the nature of the bed needing to bend. So they are 200 cm in length rather than 191 cm. King size and super king size are normally two 75 cm or two 90 cm adjacent beds. [25]
A bed frame includes head, foot, and side rails. [1] The majority of double (full) beds and all queen- and king-sized beds necessitate a central support rail, often accompanied by additional feet that extend towards the floor for stability. The concept of a "bed frame" was initially introduced and referred to between 1805 and 1815. [1]
Bed frames, also called bed steads, are made of wood or metal. The frame is made up of head, foot, and side rails. For heavy duty or larger frames (such as for queen- and king-sized beds), the bed frame also includes a center support rail. The rails are assembled to create a box for the mattress or mattress/box spring to sit on. Types include:
For example, the tert-butyl group (A-value=4.9) has a larger A-value than the trimethylsilyl group (A-value=2.5), yet the tert-butyl group actually occupies less space. This difference can be attributed to the longer length of the carbon–silicon bond as compared to the carbon–carbon bond of the tert-butyl group.
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